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Effect of the cryst...
Effect of the crystal structure on the optical properties and Ag sensitization of Tb3+/Yb3+ ions in silica-zirconia glasses and glass-ceramics
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- Enrichi, Francesco (författare)
- Department of Computer Science, University of Verona, Ca' Vignal 2, Strada Le Grazie 15, 37134 Verona, Italy; CNR-ISP Institute of Polar Sciences, Via Torino 155, 30172 Mestre, Venezia, Italy
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- Cassetta, Michele (författare)
- Department of Computer Science, University of Verona, Ca' Vignal 2, Strada Le Grazie 15, 37134 Verona, Italy
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- Daldosso, Nicola (författare)
- Department of Computer Science, University of Verona, Ca' Vignal 2, Strada Le Grazie 15, 37134 Verona, Italy
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- Cattaruzza, Elti (författare)
- Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, Via Torino 155, 30172, Venezia-Mestre, Italy
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- Riello, Pietro (författare)
- Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, Via Torino 155, 30172, Venezia-Mestre, Italy
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- Zairov, Rustem (författare)
- Aleksander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, 420008, 1/29 Lobachevskogo str., Russian Federation
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- Vomiero, Alberto (författare)
- Luleå tekniska universitet,Materialvetenskap,Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, Via Torino 155, 30172, Venezia-Mestre, Italy
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- Righini, Giancarlo C. (författare)
- CNR-IFAC Nello Carrara Institute of Applied Physics, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze, Italy
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(creator_code:org_t)
- Elsevier, 2022
- 2022
- Engelska.
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Ingår i: Ceramics International. - : Elsevier. - 0272-8842 .- 1873-3956. ; 49:24 Part B
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The role of the material structure in the energy transfer between Ag and Tb3+/Yb3+ ions is studied in silica-soda-zirconia sol-gel glasses and glass-ceramics. The preparation of Tb3+ and Yb3+ doped silica-soda-zirconia layers was carried out by sol-gel and dip-coating, followed by thermal annealing. The precipitation of zirconia nanocrystals was obtained by controlling the annealing temperature: from a full amorphous glass at 700 °C into a glass-ceramic at 1000 °C. A different crystalline structure of zirconia nanocrystals, tetragonal or cubic, was controlled by the rare-earth doping and investigated in relation to the Tb3+/Yb3+ optical properties. Moreover, Ag codoping was introduced by ion-exchange, obtaining a significant photoluminescence enhancement, both in the intensity and in the broadness of the excitation band, covering the whole UV region and part of the violet-blue region. Ag-sensitized Tb3+/Yb3+ doped silica-soda-zirconia glass-ceramics were attested to be potential candidates for energy-related applications, such as spectral conversion layers for solar cells, lasers and light-emitting devices (LEDs) in the visible and NIR spectral regions.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Nyckelord
- Sol-gel
- Glass-ceramics
- Tb3+/Yb3+ ions
- Ag sensitizers
- Cubic and tetragonal zirconia
- Experimentell fysik
- Experimental Physics
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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