Adsorption Kinetics and Isotherm Study of Basic Red 5 on Synthesized Silica Monolith Particles

• The Silica monolith particles (SMP) were prepared from Tetra-Methyl-Ortho-Silicate (TMOS) and characterized by Fourier transforms infrared (FTIR), Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and surface area analyzer. FTIR analysis showed the Si-O stretching confirming SMP formation. SEM analysis provided information about the mean diameter of SMP (1-5 mu m). EDX confirmed the presence of silicon and oxygen in the SMP. Moreover, the calculated surface area for SMP was found to be around 367 m(2)/g, whereas BJH pore size distributed particles were 87.15 along with the total pore volume and pore radius of 0.073 cm(3)/g and 16.627 & ANGS;, respectively. Besides, the removal efficiency was found to be about 96%. Various kinetic equations were used to calculate the adsorption parameters. Overall, the results show that the most appropriate model for the kinetics data was the pseudo-second order kinetics model while the mechanism of adsorption was best explained by the Langmuir isotherm. The highest removal of Basic Red 5 dye after 120 min at 298 K was 576 mg/g. Moreover, the thermodynamics parameters (Enthalpy, Gibb's energy, and Entropy) were also estimated. The & UDelta;H & DEG; (0.995 kJ/mol) value depicted the endothermic nature of the process. The non-spontaneous aspect of the process was evident from the & UDelta;G & DEG; values which were 60.431, 328.93, and 339.5 kJ/mol at 293, 303, and 313 K, respectively. From the high removal efficiency value, it can be concluded that the prepared adsorbent can be a potential adsorbent in the reclamation of dyes from wastewater.

Ämnesord

NATURVETENSKAP  -- Geovetenskap och miljövetenskap -- Miljövetenskap (hsv//swe)

NATURAL SCIENCES  -- Earth and Related Environmental Sciences -- Environmental Sciences (hsv//eng)

Nyckelord

silica monolith particles

surface area analyzer

thermodynamics parameter

adsorption

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