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Palladium-catalyzed...
Palladium-catalyzed oxidative dehydrogenative carbonylation reactions using carbon monoxide and mechanistic overviews
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- Zhu, Can (författare)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
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- Liu, Jie (författare)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
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- Li, Man-Bo (författare)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden; Institute of Physical Science and Information Technology, Anhui University, Hefei, China
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- Bäckvall, Jan-Erling (författare)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
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(creator_code:org_t)
- 2020
- 2020
- Engelska.
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Ingår i: Chemical Society Reviews. - : Royal Society of Chemistry. - 0306-0012 .- 1460-4744. ; 49, s. 341-353
- Relaterad länk:
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https://pubs.rsc.org...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Carbon monoxide, which is an abundant and inexpensive carbonyl source, has been widely applied to synthesize carbonyl-containing compounds, for example ketones, esters, and amides. These types of compounds are ubiquitous in natural products, pharmaceuticals, as well as in functional materials. This review focuses on the palladium-catalyzed dehydrogenative C-H/X-H (X = C, N, O) carbonylation transformations under oxidative conditions. The related C-H bonds here include C(sp)-H, C(sp2)-H, and C(sp3)-H bonds. From a step- and atom-economy perspective, transition metal-catalyzed oxidative dehydrogenative C-H/X-H carbonylation reactions with CO constitute one of the most efficient strategies for the construction of versatile carbonyl groups, without the requirement of pre-functionalized substrates.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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