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Nano-confinement-in...
Nano-confinement-inspired metal organic framework/polymer composite separation membranes
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Li, Xiaoting (author)
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Wang, Naixin (author)
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Bao, Xinmin (author)
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Li, Qian (author)
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Li, Jie (author)
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Xie, Ya-Bo (author)
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Ji, Shulan (author)
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- Yuan, Jiayin (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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An, Quan-Fu (author)
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(creator_code:org_t)
- 2020
- 2020
- English.
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In: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 8:33, s. 17212-17218
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A defect-free, robust and selective barrier is essential for manufacturing membranes with targeted high permeability and selectivity. Here we report a new route to engineering a separation composite membrane by confining both channels in nanoscale metal organic frameworks (MOFs) and charges in a polyelectrolyte in the inner space of a porous supportviaa counter-diffusion method. A simple thermal annealing treatment of the interface between the MOF, polymer and support favorably reduced voids inside this nano-confinement environment. As this composite membrane combines both the support and barrier as one, it minimizes mass transfer resistance of water molecules. In a separation test, it readily achieved the state-of-the-art permeance. This simple chemical approach to upgrade membrane structures will offer wide opportunities in separation devices.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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