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FTIR spectral compo...
FTIR spectral components of schwertmannite
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- Boily, Jean-François (författare)
- Umeå universitet,Kemiska institutionen
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Gassman, Paul L (författare)
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Peretyazhko, Tetyana (författare)
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Szanyi, János (författare)
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Zachara, John M (författare)
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(creator_code:org_t)
- 2010-01-12
- 2010
- Engelska.
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Ingår i: Environmental Science and Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 44:4, s. 1185-1190
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Fourier transform infrared (FTIR) spectral components of three dominant groups of sulfate species in synthetic schwertmannite (Fe8O8(OH)6-x(SO4)x*nH2O) are presented. These components were extracted by multivariate curve resolution analysis of spectra obtained from N2(g)-dry samples initially reacted in aqueous solutions (pH 3-9) at room temperature. Each component contains complex sets of bands that correspond to mixtures of similar species. We tentatively assign these components to sulfate ions that are hydrogen- (components I and III) and iron-bonded (component I) to schwertmannite. Another component (II) is assigned to protonated sulfate species. Heating experiments to 130 degrees C moreover confirmed this possibility for component II. The spectral components extracted from this study can be used to identify dominant sulfate species in FTIR spectra of naturally occurring schwertmannite samples.
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- art (ämneskategori)
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