Measurement of T-1 relaxation rates of natural abundant C-13 at C2 ' in a non-uniformly deuterium-labelled oligo-DNA

• The T-1 relaxation rate of C2' at natural abundance of four different stereoselectively C2' deuterio-labelled nucleotide residues [2'-H-2 (S): similar to 85 atom% H-2, 2"-H-2 (R): similar to 15 atom% H-2: 3'- and 5'/5"-H-2: >97 atom% 2H; 4'-H-2: similar t

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NUCLEAR-MAGNETIC-RESONANCE; DYNAMIC FREQUENCY-SHIFTS; ENZYMATIC-SYNTHESIS; NMR-WINDOW; H-1-NMR WINDOW; OLIGONUCLEOTIDE DUPLEXES; STRUCTURAL FEATURES; COUPLING-CONSTANTS; HETERONUCLEAR NMR; RNA

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