Elucidation of the origin of NOEs and ROEs that show the hydration in the minor and major grooves of DNA duplex with ATTAAT tract by a combination of NOESY and ROESY experiments

• A combination of NOESY and ROESY experiments (using ammonia as a catalyst across the pH range of 5 to 8.6) has given us a clear understanding regarding the origin of nOes that are attributed to the stereochemical location and the residence time of water i

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PAIR EXCHANGE KINETICS; IMINO PROTON-EXCHANGE; AQUEOUS-SOLUTION; NMR-SPECTROSCOPY; WATER-MOLECULES; ROTATING-FRAME; B-DNA; PROTEIN HYDRATION; BOUND WATER; RNA DUPLEX

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