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Rapid and Efficient...
Rapid and Efficient Conversion of (CO2)-C-11 to (CO)-C-11 through Silacarboxylic Acids : Applications in Pd-Mediated Carbonylations
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- Nordeman, Patrik (författare)
- Uppsala universitet,Institutionen för läkemedelskemi
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- Friis, Stig D. (författare)
- Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Carbon Dioxide Activat Ctr CADIAC, DK-8000 Aarhus C, Denmark.;Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark.
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- Andersen, Thomas L. (författare)
- Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Carbon Dioxide Activat Ctr CADIAC, DK-8000 Aarhus C, Denmark.;Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark.
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- Audrain, Helene (författare)
- Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Carbon Dioxide Activat Ctr CADIAC, DK-8000 Aarhus C, Denmark.;Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark.
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- Larhed, Mats (författare)
- Uppsala universitet,Institutionen för läkemedelskemi
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- Skrydstrup, Troels (författare)
- Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Carbon Dioxide Activat Ctr CADIAC, DK-8000 Aarhus C, Denmark.;Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark.
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- Antoni, Gunnar (författare)
- Uppsala universitet,Institutionen för läkemedelskemi
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(creator_code:org_t)
- 2015-10-23
- 2015
- Engelska.
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Ingår i: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 21:49, s. 17601-17604
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Herein, we present a new rapid, efficient, and low-cost radiosynthetic protocol for the conversion of (CO2)-C-11 to (CO)-C-11 and its subsequent application in Pd-mediated reactions of importance for PET applications. This room-temperature methodology, using readily available chemical reagents, is carried out in simple glass vials, thus eliminating the need for expensive and specialized high-temperature equipment to access (CO)-C-11. With this fast and near-quantitative conversion of (CO2)-C-11 into (CO)-C-11, aryl and heteroaryl iodides were easily converted into a broad selection of biologically active amides in radiochemical yields ranging from 29-84 %.
Ämnesord
- MEDICIN OCH HÄLSOVETENSKAP -- Medicinska och farmaceutiska grundvetenskaper -- Läkemedelskemi (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Basic Medicine -- Medicinal Chemistry (hsv//eng)
Nyckelord
- carbon monoxide
- carbon-11
- carbon dioxide fixation
- positron emission tomography
- radiochemistry
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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