BASE-PAIR EXCHANGE KINETICS OF THE IMINO AND AMINO PROTONS OF THE 3'-PHENAZINIUM TETHERED DNA-RNA DUPLEX, R((5')GAUUGAA(3'))-D((5')TCAATC(3')-PZN), AND THEIR COMPARISON WITH THOSE OF B-DNA DUPLEX

• The dynamics of the opening-closing of the constituent base-pairs as well as of the exchange kinetics of the base-paired imino and amino protons with water in a DNA-RNA hybrid, [(5')r(G(1)A(2)U(3)U(4)G(5)A(6)A(7))(3')]:(5')p[d(T(8)C(9)A(10)A(11)T(12)C-13)

Nyckelord

IMINO PROTON; AMINO PROTON; DNA RNA DUPLEX; B-DNA DUPLEX; EXCHANGE KINETICS; D(C-G-C-G-A-A-T-T-C-G-C-G) DOUBLE HELIX; NMR-SPECTROSCOPY; NOE SPECTROSCOPY; AQUEOUS-SOLUTION; ROTATING-FRAME; SEQUENCE; OLIGONUCLEOTIDE; OFFSET; RECOGNITION; BINDING

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