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Binary superlattice...
Binary superlattice ceramic membrane-coated soft carbon/hard carbon microspheres for high energy mixed-ion batteries
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- Zhang, Xudong (författare)
- Qilu Univ Technol, Coll Mat Sci & Engn, Shandong Acad Sci, Jinan 250353, Shandong, Peoples R China
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- Bi, Zhiying (författare)
- Qilu Univ Technol, Coll Mat Sci & Engn, Shandong Acad Sci, Jinan 250353, Shandong, Peoples R China
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- Xu, Guogang (författare)
- Shandong Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266590, Shandong, Peoples R China
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- Li, Changgang (författare)
- Qilu Univ Technol, Coll Mat Sci & Engn, Shandong Acad Sci, Jinan 250353, Shandong, Peoples R China
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- He, Wen (författare)
- Qilu Univ Technol, Coll Mat Sci & Engn, Shandong Acad Sci, Jinan 250353, Shandong, Peoples R China
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- Zhu, Jie-Fang (författare)
- Uppsala universitet,Strukturkemi
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(creator_code:org_t)
- ELSEVIER, 2019
- 2019
- Engelska.
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Ingår i: Journal of Power Sources. - : ELSEVIER. - 0378-7753 .- 1873-2755. ; 438
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The assembly of two different materials into a composite with binary superlattices can provide a most efficient and inexpensive path to the synthesis of electrode materials with high energy density. Here, Li9Fe3P8O29/Na2HPO4 binary superlattice ceramic membrane-coated mesoporous soft carbon/hard carbon microspheres (BSLCM-MSC/HCMs) are synthesized via a hydrothermal carbonization method using acyl nucleoside triphosphate disodium salt (Na(2)ATP) as a multifunctional template. Here Na(2)ATP is not only a phosphorus source, a sodium source and a nucleating agent for the rapid synthesis of BSLCM, but also is a carbon source which is easily transformed into MSC/HCMs after being heat-treated in a N-2 atmosphere. This special structure design brings a remarkable synergic effect for both Li+/Na+ mixed-ion storage and transfer kinetics. As a new nanocomposite cathode for mixed-ion batteries (MIBs), the BSLCM-MSC/HCMs display a self-enhancement of discharge capacity via electrolyte penetration in the core-shell mesoporous microspheres. Importantly, the discharge specific energy of a MIB assembled with the BSLCM-MSC/HCMs-2 cathode is up to 400 W h kg(-1) at a high current rate of 10C, which outperforms all lithium-ion batteries and sodium-ion batteries reported so far. The findings in this study may benefit to the development of high energy mixed-ion batteries.
Ämnesord
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Nyckelord
- Binary superlattice
- Ceramic membrane
- Hard carbon
- Core-shell mesoporous microsphere
- Mixed-ion battery cathode
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- ref (ämneskategori)
- art (ämneskategori)
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