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The electronic stru...
The electronic structure and lithiation of electrodes based on vanadium-oxide nanotubes
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- Augustsson, A (författare)
- Uppsala universitet,Fysiska institutionen,Strukturkemi,Fysik II
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Schmitt, T (författare)
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- Duda, L (författare)
- Uppsala universitet,Fysiska institutionen,Strukturkemi,Fysik II
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visa fler...
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- Nordgren, J (författare)
- Uppsala universitet,Fysiska institutionen,Strukturkemi,Fysik II
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- Nordlinder, Sara (författare)
- Uppsala universitet,Strukturkemi,Fysik II,strukturkemi
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- Edström, Kristina (författare)
- Uppsala universitet,Strukturkemi,Fysik II,strukturkemi
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- Gustafsson, Torbjörn (författare)
- Uppsala universitet,Strukturkemi,Fysik II,strukturkemi
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Guo, J H (författare)
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visa färre...
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(creator_code:org_t)
- 2003
- 2003
- Engelska.
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Ingår i: Journal of Applied Physics. ; 94:8, s. 5083-5087
- Relaterad länk:
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https://urn.kb.se/re...
Abstract
Ämnesord
Stäng
- The synthesis of a novel ligand 2′-[1-(2-pyridinyl)-ethylidene]-oxamohydrazide (Hapsox), from a series of 2-acetylpyridine acylhydrazones, and its complex with Co(III), which is the first in this series of complexes are described. Both the ligand and the complex were characterized by elemental analysis, IR, 1H-NMR, and 13C-NMR spectra, and the structure of the complex [Co(apsox)2]ClO4 was determined by X-ray structural analysis. It was established that [Co(apsox)2]ClO4 has an octahedral geometry with two tridentate apsox ligands in monoanionic form. Structural characteristics, lengths of the bonds, and angles between the bonds were typical for Co(III) complexes of distorted octahedral geometry. Both direct and template synthesis afforded the same geometrical isomer of the complex with two apsox ligands meridionally bound to the central metal ion, even in the case when equimolar quantities of Co(ClO4)2 and Hapsox were applied.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Nyckelord
- Inorganic chemistry
- Oorganisk kemi
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- ref (ämneskategori)
- art (ämneskategori)
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