Electron-Beam-Induced Fluorination Cycle for Long-Term Preservation of Graphene under Ambient Conditions

• The aging in air inevitably results in the accumulation of airborne hydrocarbon contaminations on a graphene surface, which causes considerable difficulties in the subsequent application of graphene. Herein, we report an electron-beam-activated fluorination/defluorination cycle for achieving a long-term preservation of CVD graphene. After experiencing such cycle, the accumulation of airborne hydrocarbon on the graphene surfaces is strongly reduced, and the initial chemical status of graphene can be restored, which is confirmed by employing atomic force microscopy and X-ray photoelectron microscopy. Our reported approach provides an efficient method for the cleaning and long-term preservation of graphene, and it is particularly useful for graphene microscopy characterizations.

Ämnesord

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

Nyckelord

graphene

electron-beam-induced deposition

fluorination

airborne contamination

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