Limitations of polyacrylic acid binders when employed in thick LNMO Li-ion battery electrodes

• Polyacrylic acid (PAA) is here studied as a binder material for LiNi0.5Mn1.5O4 (LNMO) cathodes for lithium-ion batteries. When the LNMO electrodes are fabricated with an active mass loading of similar to 10 mg cm-2 (similar to 1.5 mA h cm-2), poor discharge capacity and short cycle life is obtained in full-cells with graphite electrodes. The electrochemical results with PAA are compared with a commonly used water-based binder, sodium carboxymethyl cellulose (CMC), which shows better electrochemical performance. The main cause for these problems in PAA based cells is identified to be the high internal resistance in the initial cycles, caused by factors such as contact resistance, inhomogeneous binder distribution and poor electrolyte wetting of the active material.

Subject headings

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

Publication and Content Type

ref (subject category)

art (subject category)