Two-dimensional emission quenching and charge separation using a Ru(II)-photosensitizer assembled with membrane-bound acceptors

• Novel syntheses of the bipyridine ligand 1, dcHb (dcHb = 4,4'-dicarboxy-2,2'-bipyridine), by anionic oxidation of 4,4'-dimethyl-2',2-bipyridine (dmb) using molecular oxygen (4 atm), and of the sensitizer precursor 4, tris(4,4'-diethoxycarbonyl-2,2'-bipyri

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PHOTOINDUCED ELECTRON-TRANSFER; METHYL VIOLOGEN; RUTHENIUM(II) COMPLEXES; ENERGY-TRANSFER; RATE CONSTANTS; NOBEL LECTURE; DIFFUSION; PHOTOCHEMISTRY; SYSTEMS; WATER

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