Transition from a molecular to a metallic adsorbate system: Core-hole creation and decay dynamics for CO coordinated to Pd

• Two alternative methods to experimentally monitor the development of a CO-adsorption system that gradually changes from molecular to metallic are presented: firstly by adsorption of CO on Pd islands of increasing size deposited under UHV conditions, and s

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RAY PHOTOELECTRON-SPECTROSCOPY; PHOTOEMISSION SPECTRA; ABSORPTION SPECTROSCOPY; ELECTRON-SPECTROSCOPY; GAS-PHASE; SHAKE-UP; CLUSTERS; STATES; ADSORPTION; AUGER

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