New Pyrazolino- and Pyrrolidino[60]fullerenes with Transition-Metal Chelating Pyridine Substitutents: Synthesis and Complexation to Ru(II)

• Three pyridine-substituted fullerene adducts, bis(2,2'-bipyridine)(2'-phenyl-5'-(2-pyridinyl)-2'H-[5.6]fullereno(C60-Ih)[1,9]pyrazole)ruthenium-bis-(hexafluorphosphate) (1), bis(2,2'-bipyridine)(2'-phenyl-5'-(4-(4'-methyl-2,2'-bipyridinyl)-2'H[5,6]fulleroneo(C60-Ih)[1,9]pyrazole)ruthenium-bis(hexafluorophosphate)(2), and bis(2,2'-bipyridine)(1',5'-dihydro-3'-methyl-2'-(4(4'-methyl-2,2'-bipyridinyl))-2'H-[5,6]fullereno(C60-Ih)[1,9]pyrrole)ruthenium-bis(hexafluorophosphate) 83), have been prepared. The common features for these complexes are the short bridges between he fullerene and the pyridine moities.

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NATURVETENSKAP  -- Kemi -- Organisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Organic Chemistry (hsv//eng)

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Organic chemistry

Organisk kemi

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