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Absolute core-level...
Absolute core-level binding energy shifts between atom and solid: The Born-Haber cycle revisited for free nanoscale metal clusters
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- Tchaplyguine, Maxim (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
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- Peredkov, S. (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Rosso, Aldana (author)
- Uppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap
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- Bradeanu, Ioana (author)
- Uppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap
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- Öhrwall, Gunnar (author)
- Uppsala University
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- Legendre, Sébastien (author)
- Uppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap
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- Svensson, S. (author)
- Uppsala universitet,Uppsala University,Lund University,Lunds universitet,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Yt- och gränsskiktsvetenskap
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- Mårtensson, Nils (author)
- Uppsala University,Lund University,Lunds universitet,Uppsala universitet,Yt- och gränsskiktsvetenskap,MAX IV-laboratoriet,MAX IV Laboratory
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- Svensson, Svante (author)
- Uppsala universitet,Yt- och gränsskiktsvetenskap
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- Björneholm, Olle (author)
- Lund University,Lunds universitet,Uppsala universitet,Yt- och gränsskiktsvetenskap,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Ristinmaa Sörensen, Stacey (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- Elsevier BV, 2008
- 2008
- English.
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In: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 166, s. 38-44
- Related links:
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http://dx.doi.org/10...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Core-level binding energy shifts between the free atom and corresponding large clusters, the latter closely approximating the infinite solid, have been experimentally derived for several elemental metals. The cluster core-level binding energies in question have been determined relative to the vacuum level using synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest uncertainty factors defining the discrepancies between the experiment and the model, such as the difference in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster work functions, and the metal solvation energy, are discussed.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Keyword
- Nanoscale clusters
- Electronic structure
- Electron spectroscopy
- Physics
- Fysik
- Nanoscale clusters
- Electron spectroscopy
- Electronic structure
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Tchaplyguine, Ma ...
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Peredkov, S.
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Rosso, Aldana
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Bradeanu, Ioana
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Öhrwall, Gunnar
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Legendre, Sébast ...
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show more...
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Svensson, S.
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Mårtensson, Nils
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Svensson, Svante
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Björneholm, Olle
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Ristinmaa Sörens ...
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Atom and Molecul ...
- Articles in the publication
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Journal of Elect ...
- By the university
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Uppsala University
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Lund University