Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic

• The first model of the iron hydrogenase active site has been prepared in which an amine ligand is loosely coordinated to an Fe-I centre, and can be replaced by a solvent molecule; irrespective of the ligand set, the one electron reduction of both complexes is chemically reversible and is shown to proceed through the same species which features a bridging CO ligand.

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NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Nyckelord

Chemistry

Kemi

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