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Efficiency enhancem...
Efficiency enhancement in dye sensitized solar cells using gel polymer electrolytes based on a tetrahexylammonium iodide and MgI2 binary iodide system
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- Bandara, T M W J, 1968 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology,University of Peradeniya
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- Dissanayake, M. (författare)
- National Institute of Fundamental Studies
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Jayasundara, W. (författare)
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- Albinsson, Ingvar, 1962 (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),University of Gothenburg
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- Mellander, Bengt-Erik, 1949 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2012
- 2012
- Engelska.
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Ingår i: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 14:24, s. 8620-8627
- Relaterad länk:
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http://dx.doi.org/10...
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https://gup.ub.gu.se...
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https://doi.org/10.1...
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https://research.cha...
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Abstract
Ämnesord
Stäng
- Quasi-solid-state dye-sensitized solar cells have drawn the attention of scientists and technologists as a potential candidate to supplement future energy needs. The conduction of iodide ions in quasi-solid-state polymer electrolytes and the performance of dye sensitized solar cells containing such electrolytes can be enhanced by incorporating iodides having appropriate cations. Gel-type electrolytes, based on PAN host polymers and mixture of salts tetrahexylammonium iodide (Hex(4)N(+)I(-)) and MgI2, were prepared by incorporating ethylene carbonate and propylene carbonate as plasticizers. The salt composition in the binary mixture was varied in order to optimize the performance of solar cells. The electrolyte containing 120% Hex(4)N(+)I(-) with respect to weight of PAN and without MgI2 showed the highest conductivity out of the compositions studied, 2.5 x 10(-3) S cm(-1) at 25 degrees C, and a glass transition at -102.4 degrees C. However, the electrolyte containing 100% Hex(4)N(+)I(-) and 20% MgI2 showed the best solar cell performance highlighting the influence of the cation on the performance of the cell. The predominantly ionic behaviour of the electrolytes was established from the dc polarization data and all the electrolytes exhibit iodide ion transport. Seven different solar cells were fabricated employing different electrolyte compositions. The best cell using the electrolyte with 100% Hex(4)N(+)I(-) and 20% MgI2 with respect to PAN weight showed 3.5% energy conversion efficiency and 8.6 mA cm(-2) short circuit current density.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Nyckelord
- photovoltaic performance
- nanocrystalline tio2
- ionic-conductivity
- composite
- films
- conversion
- complex
- lithium
- layer
- peo
- films
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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