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Synthesis and Characterization of Iron(III) Complexes of a New Ligand Containing a Potentially Bridging Carboxylate; Structural Characterization of Helical Tetranuclear Iron Complex
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Trukhan, Vladimir M (författare)
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Pierpont, Cortlandt G (författare)
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- Nordlander, Ebbe (författare)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Shteinman, Albert A (författare)
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 1999
- Engelska.
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Ingår i: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1364-548X .- 1359-7345. ; :13, s. 1193-1194
- Relaterad länk:
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http://dx.doi.org/10...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Reaction of the new polydentate ligand 2,6-bis{3-[N,N-di(2-pyridylmethyl)amino]propoxy}benzoic acid (LH) with Fe(ClO4)3 followed by addition of chloroacetic acid leads to the formation of the tetranuclear complex [{Fe2OL(ClCH2- CO2)2}2](ClO4)4, the crystal structure of which reveals that it consists of two FeII2(µ-O)(µ-RCO2)2 cores that are linked via the two L ligands in a helical structure, with the carboxylate moieties of the two ligands forming a hydrogen-bonded pair at the center of the helix.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)