Y2Mo3O12–Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode catalyst for proton-conducting solid oxide fuel cells

• The mismatch of the coefficients of thermal expansion between cathode and electrolyte is one of the thorniest problems for high-performance proton-conducting solid oxide fuel cells (H–SOFCs). Here one strategy is applied by introducing the negative thermal expansion component, Y2Mo3O12 (YMO), on Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) cathode to overcome this difficulty. As a result, not only the electrolyte-cathode connection but also the cell performance is improved. The maximum power density of the cell using a composite cathode reaches 1010.9 mW cm−2 at 700 °C. The YMO softens the stress on the contact layer that keeps the cathode from delamination, which is confirmed by simulation studies and experiments. Furthermore, the A-site defect on BSCF created by the reaction between YMO and BSCF also plays a positive role in the oxygen reduction reaction (ORR) activity. This study provided a new way to study and improve the thermo-mechanical stability and cell performance of H–SOFCs.

Ämnesord

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Chemical Engineering (hsv//eng)

Nyckelord

BaSrCoFeO

Cathode catalyst

Proton-conductor

SOFC

Thermal expansion

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