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Quasielastic neutro...
Quasielastic neutron scattering of hydrated BaZr(0.90)A(0.10)O(2.95) (A = Y and Sc)
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- Karlsson, Maths (författare)
- Lund University,Lunds universitet,European Spallation Source ESS AB,Stiftelser och övriga anknutna verksamheter,Other Institutions and Utilities
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Matic, Aleksandar (författare)
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Engberg, Dennis (författare)
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Bjorketun, Marten E. (författare)
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Koza, Michael M. (författare)
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Ahmed, Istaq (författare)
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Wahnstroem, Goeran (författare)
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Borjesson, Lars (författare)
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Eriksson, Sten-G. (författare)
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(creator_code:org_t)
- Elsevier BV, 2009
- 2009
- Engelska.
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Ingår i: Solid State Ionics. - : Elsevier BV. - 0167-2738. ; 180:1, s. 22-28
- Relaterad länk:
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http://dx.doi.org/10...
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http://arxiv.org/pdf...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Proton motions in hydrated proton conducting perovskites BaZr(0.90)A(0.10)O(2.95) (A = Y and Sc) have been investigated using quasielastic neutron scattering. The results reveal a localized motion on the ps time scale and with an activation energy of similar to 10-30 meV, in both materials. The temperature dependence of the total mean square displacement of the protons shows an onset of this motion at a temperature of about 300 K. The low activation energy, much lower than the activation energy for the macroscopic proton conductivity, suggests that this motion is not the rate-limiting process for the long-range proton diffusion, i.e. it is not linked to the two materials significantly different proton conductivities. In fact, a comparison of the QENS results with density functional theory calculations indicates that for both materials the observed motion may be ascribed to intra-octahedral proton transfers occurring close to a dopant atom. (C) 2008 Elsevier B.V. All rights reserved.
Ämnesord
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Nyckelord
- Proton conducting
- Perovskite
- Quasielastic neutron scattering
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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