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Palladium(II) Halid...
Palladium(II) Halide Complexes I. Stabilities and Spectra of Palladium(II) Chloro and Bromo Aqua Complexes
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- Elding, Lars Ivar (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 1972
- 1972
- English 5 s.
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In: Inorganica Chimica Acta. - 0020-1693. ; 6, s. 647-651
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Abstract
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- Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
- Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Palladium(II)
- Chloride complex
- Bromide complex
- Stability constants
- Absorbance spectra
Publication and Content Type
- art (subject category)
- ref (subject category)
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