Sökning: id:"swepub:oai:research.chalmers.se:451c25dc-00c3-4675-bd58-14b17a47ec3c" >
Prospects for Impro...
Prospects for Improved Magnesocene-Based Magnesium Battery Electrolytes
-
- Jankowski, Piotr, 1990 (författare)
- Politechnika Warszawska,Warsaw University of Technology,Chalmers tekniska högskola,Chalmers University of Technology,Danmarks Tekniske Universitet,Technical University of Denmark,Alistore - European Research Institute,Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden.;Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland.;ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.;Tech Univ Denmark, Dept Energy Convers & Storage, DK-2800 Lyngby, Denmark.
-
- Schwarz, Rainer (författare)
- Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Wurttembergstiftung (ZSW),ZSW Zentrum Sonnenenergie & Wasserstoff, Forsch Baden Wurttemberg, D-89081 Ulm, Germany.
-
- Randon-Vitanova, Anna (författare)
- Honda R&D Europe (Tyskland) GmbH,Honda R&D Europe (Germany) GmbH,Honda R&D Europe Deutschland GmbH, D-63073 Offenbach, Germany.
-
visa fler...
-
- Younesi, Reza (författare)
- Uppsala universitet,Strukturkemi,ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.
-
- Wachtler, Mario (författare)
- Uppsala universitet,Strukturkemi,ZSW Zentrum Sonnenenergie & Wasserstoff, Forsch Baden Wurttemberg, D-89081 Ulm, Germany.
-
- Johansson, Patrik, 1969 (författare)
- Alistore - European Research Institute,Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden.;ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.
-
visa färre...
-
(creator_code:org_t)
- 2021-05-05
- 2021
- Engelska.
-
Ingår i: Batteries and Supercaps. - : Wiley. - 2566-6223. ; 4:8, s. 1335-1343
- Relaterad länk:
-
https://research.cha... (primary) (free)
-
visa fler...
-
https://doi.org/10.1...
-
https://doi.org/10.1...
-
https://uu.diva-port... (primary) (Raw object)
-
https://doi.org/10.1...
-
https://research.cha...
-
https://urn.kb.se/re...
-
visa färre...
Abstract
Ämnesord
Stäng
- Magnesium batteries are currently attracting a lot of interest as a next generation battery technology. One critical issue is to find a suitable electrolyte and herein we explore an electrolyte based on magnesocene (MgCp2) in tetrahydrofuran (THF), aiming for low-voltage Mg batteries, with respect to: Mg plating characteristics, electrochemical stability windows, electrolyte speciation, and electrolyte decomposition reactions; both experimentally and computationally. Overall, the electrolyte does not seem to decompose on a Mg metal anode and most likely reduced solvation of Mg2+ by the Cp- anion is important and species such as MgCp2THF2 may play an important role for Mg plating with small overpotential. The oxidation limit is largely determined by the Cp- anion and density functional theory predicted oxidation reactions point to polymerized end-products to be possible. Furthermore, in silico substitution studies enable us to establish the prospects of some Cp- anion derivatives to further improve the oxidative stability, but still the Mg2+ solvation must be monitored for ease of reduction and Mg plating.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- density functional theory
- electrolyte decomposition reactions
- bis(cyclopentadienyl) magnesium
- magnesium electroplating
- electrochemical stability window
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
Hitta via bibliotek
Till lärosätets databas