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Differences in surf...
Differences in surface chemistry of regenerated lignocellulose fibers determined by chemically sensitive scanning probe microscopy
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- Gusenbauer, Claudia (författare)
- Universität für Bodenkultur,University of Natural Resources and Life Sciences
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- Nypelö, Tiina, 1982 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Jakob, Devon S. (författare)
- Lehigh University
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- Xu, Xiaoji G. (författare)
- Lehigh University
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- Vezenov, Dmitri V. (författare)
- Lehigh University
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- Asaadi, Shirin (författare)
- Aalto-Yliopisto,Aalto University
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- Sixta, Herbert (författare)
- Aalto-Yliopisto,Aalto University
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- Konnerth, Johannes (författare)
- Universität für Bodenkultur,University of Natural Resources and Life Sciences
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(creator_code:org_t)
- Elsevier BV, 2020
- 2020
- Engelska.
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Ingår i: International Journal of Biological Macromolecules. - : Elsevier BV. - 0141-8130 .- 1879-0003. ; 165, s. 2520-2527
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https://research.cha... (primary) (free)
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https://doi.org/10.1...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Tuning the composition of regenerated lignocellulosic fibers in the production process enables targeting of specific material properties. In composite materials, such properties could be manipulated by controlled heterogeneous distribution of chemical components of regenerated fibers. This attribute requires a visualization method to show their inherent chemical characteristics. We compared complementary microscopic techniques to analyze the surface chemistry of four differently tuned regenerated lignocellulosic fibers. Adhesion properties were visualized with chemical force microscopy and showed contrasts towards hydrophilic and hydrophobic atomic force microscopy tips. Fibers containing xylan showed heterogeneous adhesion properties within the fiber structure towards hydrophilic tips. Additionally, peak force infrared microscopy mapped spectroscopic contrasts with nanometer resolution and provided point infrared spectra, which were consistent to classical infrared microscopy data. With this setup, infrared signals with a spatial resolution below 20 nm reveal chemical gradients in specific fiber types.
Ämnesord
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Pappers-, massa- och fiberteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Paper, Pulp and Fiber Technology (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
Nyckelord
- Ioncell-F
- Atomic force microscopy
- Lignocellulose
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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