Sökning: id:"swepub:oai:research.chalmers.se:77a3243f-e554-4a6c-a4ce-2e57cfc962e0" >
Hydrophilic Conjuga...
Hydrophilic Conjugated Polymers for Sustainable Fabrication of Deep-Red Light-Emitting Electrochemical Cells
-
- Filate, Tadele Tamenu, 1994 (författare)
- Addis Ababa University,Chalmers tekniska högskola,Chalmers University of Technology,Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden; Department of Chemistry, Addis Ababa University, PO Box 33658, Addis Ababa, Ethiopia
-
- Tang, Shi (författare)
- Umeå universitet,Institutionen för fysik,Umeå University
-
- Wolkeba, Zewdneh Genene, 1983 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology,Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden
-
visa fler...
-
- Edman, Ludvig, 1967- (författare)
- Umeå universitet,Institutionen för fysik,Umeå University
-
- Mammo, W. (författare)
- Addis Ababa University,Department of Chemistry, Addis Ababa University, PO Box 33658, Addis Ababa, Ethiopia
-
- Wang, Ergang, 1981 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology,Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden
-
visa färre...
-
(creator_code:org_t)
- John Wiley & Sons, 2024
- 2024
- Engelska.
-
Ingår i: Advanced Materials Technologies. - : John Wiley & Sons. - 2365-709X. ; 9:3
- Relaterad länk:
-
https://research.cha... (primary) (free)
-
visa fler...
-
https://doi.org/10.1...
-
https://umu.diva-por... (primary) (Raw object)
-
https://research.cha...
-
https://doi.org/10.1...
-
https://urn.kb.se/re...
-
visa färre...
Abstract
Ämnesord
Stäng
- It is crucial to develop functional electronic materials that can be processed from green solvents to achieve environmentally sustainable and cost-efficient printing fabrication of organic electronic devices. Here, the design and cost-efficient synthesis of two hydrophilic and emissive conjugated polymers, TQ-OEG and TQ2F-OEG, are presented, which are rendered hydrophilic through the grafting of oligo(ethylene glycol) (OEG) solubilizing groups onto the thiophene-quinoxaline conjugated backbone and thereby can be processed from a water:ethanol solvent mixture. It is shown that the introduction of the OEG groups enables for a direct dissolution of salts by the neat polymer for the attainment of solid-state ion mobility. These properties are utilized for the design and development of light-emitting electrochemical cells (LECs), the active materials of which can be solution cast from a water:ethanol-based ink. It is specifically shown that such an LEC device, comprising an optimized blend of the TQ2F-OEG emitter and a Li salt as the active material positioned between two air-stabile electrodes, delivers deep-red emission (peak wavelength = 670 nm) with a radiance of 185 µW m−2 at a low drive voltage of 2.3 V. This study contributes relevant information as to how polymers and LEC devices can be designed and fabricated to combine functionality with sustainability.
Ämnesord
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Fysik -- Annan fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Other Physics Topics (hsv//eng)
Nyckelord
- Hansen solubility parameters
- light-emitting electrochemical cells
- oligo(ethylene glycol)
- conjugated polymers
- aqueous-processable polymers
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
Hitta via bibliotek
Till lärosätets databas