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Open-Circuit Voltag...
Open-Circuit Voltage Modulations on All-Polymer Solar Cells by Side Chain Engineering on 4,8-Di(thiophen-2-yl)benzo[1,2- b:4,5- b′]dithiophene-Based Donor Polymers
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- Alkadir Abdulahi, Birhan, 1985 (författare)
- Addis Ababa University,Chalmers tekniska högskola,Chalmers University of Technology
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- Xu, Xiaofeng, 1984 (författare)
- Linköpings universitet,Linköping University
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- Murto, Petri Henrik, 1984 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Inganäs, O.W. (författare)
- Linköpings universitet,Linköping University
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- Mammo, W. (författare)
- Addis Ababa University
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- Wang, Ergang, 1981 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2018-05-30
- 2018
- Engelska.
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Ingår i: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 1:6, s. 2918-2926
- Relaterad länk:
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- In recent years, all-polymer solar cells (all-PSCs), incorporating active layers based on blends of electron-donor (D) and acceptor (A) polymers, have drawn attention because of the advantages they hold in the flexibility of choosing the D:A combinations to modulate their energy levels and to improve their overall open-circuit voltages (V oc ) and power conversion efficiencies (PCE)s. V oc is one of the key parameters for the determination of the PCEs of PSCs. In this work, we synthesized six donor polymers with three different side chains appended to the 4,8-di(thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene (BDT) units. By substituting carbon with sulfur and silicon atoms at the 5-position of the thiophenes attached to the BDT units, the highest occupied molecular orbital (HOMO) levels of the donor polymers could be successfully lowered. As anticipated, the V oc values of the resulting all-PSCs increased along with the lowering of the HOMO levels of the donor polymers. Among the six all-PSCs, the PBDT-BDD:PNDI-T10 all-PSC realized a balance between the photovoltage and photocurrent, where a decent PCE of 5.6% was obtained with a V oc of 0.9 V and a photocurrent of 10.5 mA/cm 2 .
Ämnesord
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Geovetenskap och miljövetenskap -- Annan geovetenskap och miljövetenskap (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences -- Other Earth and Related Environmental Sciences (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Polymerteknologi (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Polymer Technologies (hsv//eng)
Nyckelord
- 4,8-di(thiophen-2-yl)benzo[1,2- b:4,5- b′]dithiophene
- open-circuit voltage
- donor polymers
- side chain engineering
- all-polymer solar cells
- acceptor polymers
- organic photovoltaics
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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