Sökning: id:"swepub:oai:research.chalmers.se:e4a0bba2-004a-4b5a-973a-968677f27dcb" >
Photo- and Collisio...
Photo- and Collision-Induced Isomerization of a Charge-Tagged Norbornadiene-Quadricyclane System
-
- Jacovella, Ugo (författare)
- University of Melbourne
-
- Carrascosa, Eduardo (författare)
- University of Melbourne
-
- Buntine, Jack T. (författare)
- University of Melbourne
-
visa fler...
-
- Ree, Nicolai (författare)
- Köpenhamns universitet,University of Copenhagen
-
- Mikkelsen, Kurt V. (författare)
- Köpenhamns universitet,University of Copenhagen
-
- Jevric, Martyn, 1973 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Moth-Poulsen, Kasper, 1978 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Bieske, Evan J. (författare)
- University of Melbourne
-
visa färre...
-
(creator_code:org_t)
- 2020-06-15
- 2020
- Engelska.
-
Ingår i: Journal of Physical Chemistry Letters. - : American Chemical Society (ACS). - 1948-7185. ; 11:15, s. 6045-6050
- Relaterad länk:
-
https://research.cha... (primary) (free)
-
visa fler...
-
https://pubs.acs.org...
-
https://doi.org/10.1...
-
https://research.cha...
-
https://research.cha...
-
visa färre...
Abstract
Ämnesord
Stäng
- Molecular photoswitches based on the norbornadiene-quadricylane (NBD-QC) couple have been proposed as key elements of molecular solar thermal energy storage schemes. To characterize the intrinsic properties of such systems, reversible isomerization of a charge-tagged NBD-QC carboxylate couple is investigated in a tandem ion mobility mass spectrometer, using light to induce intramolecular [2 + 2] cycloaddition of NBD carboxylate to form the QC carboxylate and driving the back reaction with molecular collisions. The NBD carboxylate photoisomerization action spectrum recorded by monitoring the QC carboxylate photoisomer extends from 290 to 360 nm with a maximum at 315 nm, and in the longer wavelength region resembles the NBD carboxylate absorption spectrum recorded in solution. Key structural and photochemical properties of the NBD-QC carboxylate system, including the gas-phase absorption spectrum and the energy storage capacity, are determined through computational studies using density functional theory.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
Hitta via bibliotek
Till lärosätets databas