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- Lyxell, D G, et al.
(author)
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Multicomponent polyanions. 53. Structure of tetrakis(trimethylammonium) tetra-mu-oxo-bis(triaquahexadecaoxo(trioxophenylphosphato)hexamolybdate) dihydrate, [NH(CH3)(3)](4)[{(C6H5P)Mo6O21(H2O)(3)}(2)].2H(2)O
- 1998
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In: Acta Crystallographica Section B. - 0108-7681 .- 1600-5740. ; 54, s. 424-430
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Journal article (peer-reviewed)abstract
- The title compound crystallized in the monoclinic space group P2(1)/n (No. 14) [a = 11.211 (5), b = 12.862 (3), c = 23.05 (1) Angstrom, beta = 94.37 (3)degrees, V = 3314 (2) Angstrom(3), Z = 2]. The polyanion can be regarded as a dimer of a phenylphosphonatohexamolybdate, (C6H5P)Mo6O23(H2O)(3), Linked by four O atoms. In this monomeric unit the six molybdenum octahedra are grouped into two parts consisting of four and two edge-sharing octahedra, respectively. These two parts are connected by two corner-sharing O atoms to form a bent Mo-6 ring. The phenylphosphonate group coordinates to the Mo-6 ring from the narrow side as a tripodal Ligand. The {(C6H5P)Mo6O21 (H2O)(3)}(2) units form layers parallel to (001) and the structure is stabilized by hydrogen bonds between water and neighboring anions. The monomeric unit has been shown to be a key structure in the process of deducing the aqueous solution structures of the (C6H5P)Mo-6(2-) and (C6H5P)Mo-7(4-) species found in a previous equilibrium study of the H+-MoO42-(C6H5P)O-3(2-) system.
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| 2. |
- Lyxell, D G, et al.
(author)
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Multicomponent polyanions. 54. Crystal structure of tetracaesium monohydrogen phosphato(phosphito)pentamolybdate dihydrate, Cs-4[H(HP)PMo5O22]center dot 2H(2)O
- 1998
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In: Acta Chemica Scandinavica. - 0904-213X .- 1902-3103. ; 52:4, s. 425-430
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Journal article (peer-reviewed)abstract
- The crystal structure of tetracaesium monohydrogen phosphato (phosphito)pentamolybdate dihydrate was determined by single-crystal X-ray diffraction. The compound crystallises in the triclinic space group P (1) over bar, a=10.284(2), b= 10.791(2) and c=13.047(3) Angstrom, alpha=109.34(2), beta=99.92(2) and gamma=102.85(2)degrees, V=1283.4(5) Angstrom(3) and Z=2. The final R-values are R=0.066, wR=0.039 and S=1.3667. The H(HP)PMo5O224- anion has common features with the Strandberg X2M5-type heteropolyanion. The five MoO6 octahedra form a five-membered ring by one corner-sharing and four edge-sharing connections, and the tripodal phosphate and phosphite ligands protrude from each side of this ring in opposite directions. This is the first example of the structure of the heteropolyoxometalate having both P-III and P-V as heteroatoms.
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