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Träfflista för sökning "WFRF:(Lin J) srt2:(2005-2009);pers:(Yang T.)"

Search: WFRF:(Lin J) > (2005-2009) > Yang T.

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  • Yang, T, et al. (author)
  • Fe5O5[B6O10(OH)3]·nH2O: Wave-layered Iron Borate and Frustrated Antiferromagnetism
  • 2009
  • In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 48:23, s. 11209-11214
  • Journal article (peer-reviewed)abstract
    • The first layered iron borate, Fe5O5[B6O10(OH)3]·nH2O, has been prepared by the boric acid flux method. Its structure, determined by single crystal X-ray diffraction, contains a double FeO6-octahedral layer and an unusual [B6O13] chain. The rigid and cambered [B6O13] chains bend the octahedral layers, resulting in a wave-like and sandwiched structure. Crystallographic study indicates the structural modulation is mainly from the [B6O13] chains because of the insertion of water molecules in between. Nevertheless, FeO6 layers in the average structure, which are well separated by borate chains, is still a reasonable model to understand the two-dimensional magnetism. The strong antiferromagnetic interactions and the complex Fe3+-net suggest a possible geometrically magnetic frustration, which may be the reason for the second-order temperature-induced magnetic transition at 125 K. The condensed Fe3+ layers and the relatively low redox potential at about 1.25 V versus Li+/Li show its potentials as an anodic material.
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  • Result 1-3 of 3
Type of publication
journal article (3)
Type of content
peer-reviewed (3)
Author/Editor
Yang, T. (3)Undo refine
Zou, Xiaodong (2)
Sun, Junliang (2)
Ju, J. (2)
Chen, L (1)
Wang, Y. (1)
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Christensen, J (1)
Li, G. (1)
Deng, F (1)
He, Z. (1)
Lin, J. (1)
Wang, Y. X. (1)
Christensen, K.E. (1)
Sasaki, J (1)
Lin, JH (1)
Li, GB (1)
Lin, J. H. (1)
Liao, FH (1)
Liao, F (1)
Jang, SH (1)
Toyota, N. (1)
Li, G.B. (1)
Liao, F.H. (1)
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University
Stockholm University (3)
Language
English (3)

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