| 1. |
- Hou, Yuanyuan, et al.
(author)
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Comparative study of pressure-induced polymerization of C60 nanorods and single crystals
- 2007
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In: Journal of Physics Condensed Matter. - Bristol : Institute of Physics. - 0953-8984 .- 1361-648X. ; 19:42, s. 425207-
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Journal article (peer-reviewed)abstract
- In this paper, we report a comparative study of pressure-induced polymerization in C60 nanorods and bulk single crystals, treated simultaneously under various pressures and temperatures in the same experiment. For both materials, orthorhombic, tetragonal and rhombohedral phases have been produced under high pressure and high temperature. The structures have been identified and compared between the two sample types by Raman and photoluminescence spectroscopy. There are differences between the Raman and photoluminescence spectra from the two types of materials for all polymeric phases, but especially for the tetragonal phase. From the comparison between nanorods and bulk samples, we tentatively assign photoluminescence peaks for various polymeric phases.
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| 2. |
- Liu, Bingbing, et al.
(author)
-
High pressure and high temperature induced polymeric C60 nanocrystal
- 2008
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In: Diamond and related materials, vol. 17, issue 4-5. - Amsterdam : Elsevier B.V.. ; , s. 620-623
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Conference paper (peer-reviewed)abstract
- In this paper, C60 nanosheets with polymeric phases have been obtained under various high pressures and high temperatures, including orthorhombic and tetragonal polymeric phases. The structures have been identified and compared with those of nanorods by photoluminescence and Raman spectroscopies. The main fluorescence band shifted from 1.70 eV in the monomeric phase to near infrared in the polymeric phase when pressure and temperature were increased. The difference of photoluminescence and Raman spectra between nanosheets and nanorods samples treated under the same conditions is probably caused by different polymerization degree in these samples because of different shapes.
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