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Efficient and Gener...
Efficient and General One-Pot Synthesis of Diaryliodonium Triflates : Optimization, Scope and Limitations
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- Bielawski, Marcin (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Zhu, Mingzhao (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Olofsson, Berit (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- Wiley, 2007
- 2007
- English.
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In: Advanced Synthesis and Catalysis. - : Wiley. - 1615-4150 .- 1615-4169. ; 349:17-18, s. 2610-2618
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Symmetrical and unsymmetrical diaryliodonium triflates have been synthesized from both electron-deficient and electron-rich arenes and aryl iodides with mCPBA and triflic acid. A thorough investigation of the optimization, scope and limitations has resulted in an improved one-pot protocol that is fast, high-yielding, and operationally simple. The reaction has been extended to the direct synthesis of symmetrical iodonium salts from iodine and arenes, conveniently circumventing the need for aryl iodides.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- arenes
- aromatic substitution
- diaryliodonium salts
- hypervalent compounds
- iodine
- oxidation
- Organic chemistry
- Organisk kemi
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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