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  • Launois, Pascale (author)

Pressure polymerized C60 single crystals: First x-ray diffraction results

  • Article/chapterEnglish1998

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  • Singapore :World Scientific,1998
  • printrdacarrier

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  • LIBRIS-ID:oai:DiVA.org:umu-23483
  • https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-23483URI

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  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:kon swepub-publicationtype

Notes

  • Editors: Hans Kuzmany, Jörg Fink, Michael Mehring and Siegmar Roth.
  • C60 single crystals compressed at approx. 1 GPa and heated at about 300 C are found to polymerize in one dimension without losing their crystalline order. The resulting structure is orthrhombic, with space group Pmnn and parameters a=9.14 Å, b=9.9 Å and c=14.66 Å. The X-ray single crystal results allow us to derive a polymerization mechanism, which may also, for instance, apply to one dimensional C60 polymers in the doped compounds. The new polymer phase is discussed with respect to the C60 pressure-temperature diagram. The comparison with the A1C60 polymers raises questions about the interchain and the alkali metal - fullerene interactins.

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  • Moret, Roger (author)
  • Persson, Per-AxelUmeå universitet,Institutionen för fysik(Swepub:umu)pepe0001 (author)
  • Sundqvist, BertilUmeå universitet,Institutionen för fysik(Swepub:umu)besu0001 (author)
  • Umeå universitetInstitutionen för fysik (creator_code:org_t)

Related titles

  • In:Molecular NanostructuresSingapore : World Scientific, s. 348-3529789810232610

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