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Enhancement of Func...
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Celeste, ArcangeloUniversità degli Studi di Genova,University of Genoa,Fondazione Istituto Italiano di Tecnologia
(author)
Enhancement of Functional Properties of Liquid Electrolytes for Lithium-Ion Batteries by Addition of Pyrrolidinium-Based Ionic Liquids with Long Alkyl-Chains
- Article/chapterEnglish2020
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LIBRIS-ID:oai:research.chalmers.se:07671bfe-fb28-40e9-be7b-57764b148cbb
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https://research.chalmers.se/publication/517524URI
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https://doi.org/10.1002/batt.202000070DOI
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Three ionic liquid belonging to the N-alkyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl) imides (Pyr(1),nTFSI with n=4,5,8) have been added as co-solvent to two commonly used electrolytes for Li-ion cells: (a) 1 M lithium hexafluorophosphate (LiPF6) in a mixture of ethylene carbonate (EC) and linear like dimethyl carbonate (DMC) in 1 : 1 v/v and (b) 1 M lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI) in EC : DMC 1 : 1 v/v. These electrolyte formulations (classified as P and T series containing LiPF6 or LiTFSI salts, respectively) have been analyzed by comparing ionic conductivities, transport numbers, viscosities, electrochemical stability as well as vibrational properties. In the case of the Pyr(1,5)TFSI and Pyr(1,8)TFSI blended formulations, this is the first ever reported detailed study of their functional properties in Li-ion cells electrolytes. Overall, P-electrolytes demonstrate enhanced properties compared to the T-ones. Among the various P electrolytes those containing Pyr(1,4)TFSI and Pyr(1,5)TFSI limit the accumulation of irreversible capacity upon cycling with satisfactory performance in lithium cells.
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Silvestri, LauraENEA Centro Ricerche,ENEA Research Centre
(author)
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Agostini, Marco,1987Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)agostini
(author)
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Sadd, Matthew,1994Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)sadd
(author)
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Palumbo, StefanoFondazione Istituto Italiano di Tecnologia
(author)
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Panda, Jaya CumarFondazione Istituto Italiano di Tecnologia
(author)
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Matic, Aleksandar,1968Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)matic
(author)
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Pellegrini, VittorioFondazione Istituto Italiano di Tecnologia
(author)
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Brutti, SergioUniversita degli Studi di Roma la Sapienza,Sapienza University of Rome
(author)
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Università degli Studi di GenovaFondazione Istituto Italiano di Tecnologia
(creator_code:org_t)
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In:Batteries and Supercaps: Wiley3:10, s. 1059-10682566-6223
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