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  • Sundqvist, BertilUmeå universitet,Institutionen för fysik (author)

Physical properties of pressure polymerized C60

  • Article/chapterEnglish1996

Publisher, publication year, extent ...

  • Pennington, NJ :The Electrochemical Society,1996
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:umu-25932
  • https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-25932URI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:kon swepub-publicationtype

Notes

  • Editors: Karl M. Kadish and Rodney S. Ruoff.
  • We present in this paper an overview of the physical properties of the high pressure polymerized C60 phase commonly known as "soft fcc". This phase has been studied by several methods over wide ranges in temperature T and/or pressure, p. We present here experimental information about the specific heat capacity, the thermal expansion coefficient, the lattice structure, and the thermal conductivity, and we also show results obtained by NMR and Raman spectroscopy. All data presented agree with the accepted model that the individual molecules in this phase are covalently bound to form linear molecular chains. In particular, the NMR data show clearly the presence of covalent bonds, and the Raman data exhibit several new lines at very low energies connected with chain vibrations. Thermal conductivity data obtained during polymerization show both the time dependence of the process and that polymerization occurs at lower p and T than observed previously for this phase.

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Added entries (persons, corporate bodies, meetings, titles ...)

  • Andersson, OveUmeå universitet,Institutionen för fysik(Swepub:umu)ovan0001 (author)
  • Edlund, UlfUmeå universitet,Kemiska institutionen(Swepub:umu)uled0001 (author)
  • Fransson, ÅkeUmeå universitet,Institutionen för tillämpad fysik och elektronik(Swepub:umu)akfr0001 (author)
  • Inaba, Akira (author)
  • Jacobsson, PerUmeå universitet,Institutionen för fysik(Swepub:umu)peja0018 (author)
  • Johnels, DanUmeå universitet,Kemiska institutionen(Swepub:umu)dajo0001 (author)
  • Launois, Pascale (author)
  • Meingast, Christoph (author)
  • Moret, Roger (author)
  • Moritz, Thomas (author)
  • Persson, Per-AxelUmeå universitet,Institutionen för tillämpad fysik och elektronik,Institutionen för fysik(Swepub:umu)pepe0001 (author)
  • Soldatov, AlexanderUmeå universitet,Institutionen för fysik (author)
  • Wågberg, ThomasUmeå universitet,Institutionen för fysik(Swepub:umu)thwa0002 (author)
  • Umeå universitetInstitutionen för fysik (creator_code:org_t)

Related titles

  • In:Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, volume 3Pennington, NJ : The Electrochemical Society, s. 1014-10281566771625

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