Covalently linked ruthenium(II)-manganese(II) complexes: Distance dependence of quenching and electron transfer

• Continuing our development of artificial models for photosystem II in green plants, a series of compounds have been prepared in which a RU(bpy)(3)(2+) photosensitizer is covalently Linked to a manganese(II) electron donor. In addition to a trispicolylamin

Nyckelord

ruthenium; manganese; N ligands; electron transfer; PHOTOSYSTEM-II; MANGANESE COMPLEXES; ARTIFICIAL PHOTOSYNTHESIS; GROUND-STATE; OXYGEN; WATER; MODEL; DELOCALIZATION; RUTHENIUM(II); PORPHYRIN

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