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Sökning: onr:"swepub:oai:DiVA.org:liu-13887" > Electrophosphoresce...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003483naa a2200397 4500
001oai:DiVA.org:liu-13887
003SwePub
008060707s2004 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-138872 URI
024a https://doi.org/10.1016/j.tsf.2004.05.0952 DOI
040 a (SwePub)liu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Wang, Xiangjunu Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska högskolan4 aut0 (Swepub:liu)xinwa58
2451 0a Electrophosphorescence from substituted poly(thiophene) doped with iridium or platinum complex
264 1b Elsevier BV,c 2004
338 a print2 rdacarrier
520 a Electrophosphorescence has been observed in doped polythiophene light-emitting diodes (LEDs) with poly(3-methyl-4-octylthiophene) [PMOT] as host and the phosphorescent compounds bis(2-phenylbenzothiazole) iridium acetylacetonate (BTIr) or platinum(II) 2,8,12,17-tetraethyl-3,7,13,18-tramethyl porphyrin (PtOX) as guest. The photoluminescence (PL) and electroluminescence (EL) of host–phosphorescent guest blends PMOT:BTIr (or PMOT:PtOX) showed the existence of energy transfer from host to guest, which were guest concentration-dependent. At a certain guest concentration, emission from host PMOT was completely quenched in both blends based LEDs, and this gave rise to electrophosphorescence. The PL from host PMOT in the PMOT:BTIr blend film could not be quenched completely but was totally quenched in PMOT:PtOX. This implies a more efficient energy transfer from PMOT to PtOX than that from PMOT to BTIr under optical excitation. Comparison of PL and EL showed that the mechanism of exciton formation at the guest site under electrical excitation was not identical for these two systems. Energy transfer was a dominating route for exciton formation in PMOT:PtOX-based LEDs; charge trapping effect additionally contributed to the formation of exciton at BTIr in PMOT:BTIr-based LEDs. This study demonstrates a new direction in which polythiophene can be a candidate as a host to realize electrophosphorescence in polymer light-emitting diodes (PLEDs). Authors further indicate that to optimize the performance of the polythiophe/phosphorescent complexes, LEDs proper polythiophenes with large bang gap are needed.
653 a Polymer LED
653 a Electrophosphorescence
653 a Energy transfer
653 a Quenching of luminescence
653 a Polythiophene
653 a Phosphorescent complex
653 a NATURAL SCIENCES
653 a NATURVETENSKAP
700a Andersson, Mats R.u Department of Organic Chemistry and Polymer Technology, Chalmers University of Technology, Göteborg, Sweden4 aut
700a Thomson, Mark E.u Department of Chemistry, University of Southern California, Los Angeles, USA4 aut
700a Inganäs, Olleu Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska högskolan4 aut0 (Swepub:liu)ollin59
710a Linköpings universitetb Biomolekylär och Organisk Elektronik4 org
773t Thin Solid Filmsd : Elsevier BVg 468:1-2, s. 226-233q 468:1-2<226-233x 0040-6090x 1879-2731
856u http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-7065y Link to Ph.D. Thesis
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-13887
8564 8u https://doi.org/10.1016/j.tsf.2004.05.095

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