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- Olofsson, BeritRoyal Institute of Technology, Sweden (author)
Divergent synthesis of D-erythro-sphingosine, L-threo-sphingosine, and their regioisomers
- Article/chapterEnglish2003
Publisher, publication year, extent ...
- 2003-02-15
- American Chemical Society (ACS),2003
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-22336
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-22336URI
- https://doi.org/10.1021/jo0268254DOI
- https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-109685URI
Supplementary language notes
- Language:English
- Summary in:English
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Notes
- QC 20100525
- Starting from a vinyl epoxide, a divergent synthesis of four sphingosine isomers is described. The remaining four isomers can easily be synthesized using the same methodology. Although numerous syntheses of sphingosine have been published, this is the first general route leading to all eight isomers in this important compound class. The synthetic strategy relies on regioselective opening of a vinyl epoxide and a vinylaziridine in the allylic position.
Subject headings and genre
- NATURVETENSKAP Kemi Organisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Organic Chemistry hsv//eng
- beta-amino alcohols
- stereoselective synthesis
- enantioselective synthesis
- l-serine
- route
- regiodivergent
- derivatives
- products
- organisk kemi
Added entries (persons, corporate bodies, meetings, titles ...)
- Somfai, PeterKTH,Kemi,Royal Institute of Technology, Sweden(Swepub:kth)u1ddelvn (author)
- Royal Institute of Technology, SwedenKemi (creator_code:org_t)
Related titles
- In:Journal of Organic Chemistry: American Chemical Society (ACS)68:6, s. 2514-25170022-32631520-6904
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