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Facile synthesis of Koser's reagent and derivatives from iodine or aryl iodides
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- Merritt, Eleanor A. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Carneiro, Vania M.T. (author)
- Stockholms universitet,Institutionen för organisk kemi
- Silva Jr., Luiz F. (author)
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- (creator_code:org_t)
- 2010-10-06
- 2010
- English.
- In: Journal of Organic Chemistry. - : American Chemical Society (ACS). - 0022-3263 .- 1520-6904. ; 75:21, s. 7416-7419
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The first one-pot synthesis of neutral and electron-rich [hydroxy(tosyloxy)iodo]arenes (HTIBs) from iodine and arenes is presented, thereby avoiding the need for expensive iodine(III) precursors. A large set of HTIBs, including a polyfluorinated analogue, can be obtained from the corresponding aryl iodide under the same conditions. The reaction proceeds under mild conditions, without excess reagents, and is fast and high-yielding. Together, the two presented routes give access to a wide range of HTIBs, which are useful reagents in a variety of synthetic transformations.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Organic chemistry
- Organisk kemi
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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