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Effect of A/B-site ...
Effect of A/B-site substitution on oxygen production performance of strontium cobalt based perovskites for CO2 capture application
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- Shen, Qiuwan (författare)
- Lund University,Lunds universitet,Kraftverksteknik,Institutionen för energivetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Thermal Power Engineering,Department of Energy Sciences,Departments at LTH,Faculty of Engineering, LTH,Huazhong University of Science and Technology
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Zheng, Ying (författare)
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Luo, Cong (författare)
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Ding, Ning (författare)
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Zheng, Chu-Guang (författare)
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- Thern, Marcus (författare)
- Lund University,Lunds universitet,Kraftverksteknik,Institutionen för energivetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Thermal Power Engineering,Department of Energy Sciences,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 2015
- 2015
- Engelska.
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Ingår i: RSC Advances. - : Royal Society of Chemistry (RSC). - 2046-2069. ; 5:50, s. 39785-39790
- Relaterad länk:
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http://dx.doi.org/10...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Oxy-fuel combustion is one of the proposed technologies which have the potential to achieve zero CO2 emission. Strontium cobalt based perovskite oxygen carriers are promising materials for air separation with a high selectively for oxygen. And these perovskites can produce an oxygen enriched carbon dioxide stream for an oxy-fuel combustion process. The relatively low oxygen production yield may be a drawback of this type of material for this technology. This paper presents an effective approach by A/B-site substitution to improve the oxygen production performance of the perovskites. In this study, a series of different A/B-site substituted SrCo0.8Fe0.2O3-delta were prepared by an EDTA-citrate sol-gel combustion synthesis method. Fixed-bed experiments and TGA measurements were performed to study the effects of A/B-site substitution on cyclic oxygen adsorption/desorption performance of the synthesized samples. The experimental results indicate that the oxygen desorption amounts of different A-site substituted perovskites decrease in the order of BaCo0.8Fe0.2O3-delta > Ba0.5Sr0.5Co0.8Fe0.2O3-delta > SrCo0.8Fe0.2O3-delta > Sr0.5Ca0.5Co0.8Fe0.2O3-delta > MgCo0.8Fe0.2O3-delta. Moreover, B-site substitution by different transition metal ions can significantly modify oxygen adsorption capacity and oxygen desorption performance of SrCo0.8Fe0.2O3-delta. Furthermore, oxygen desorption performance can be improved when Fe ions of the perovskite SrCo0.8Fe0.2O3-delta are substituted by Zr, Cr, Zn, and Ni ions.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Maskinteknik -- Energiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Mechanical Engineering -- Energy Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
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