Covalently linked ruthenium(II)-manganese(II) complexes: Distance dependence of quenching and electron transfer

• Continuing our development of artificial models for photosystem II in green plants, a series of compounds have been prepared in which a RU(bpy)(3)(2+) photosensitizer is covalently Linked to a manganese(II) electron donor. In addition to a trispicolylamin

Keyword

ruthenium; manganese; N ligands; electron transfer; PHOTOSYSTEM-II; MANGANESE COMPLEXES; ARTIFICIAL PHOTOSYNTHESIS; GROUND-STATE; OXYGEN; WATER; MODEL; DELOCALIZATION; RUTHENIUM(II); PORPHYRIN

Publication and Content Type

ref (subject category)

art (subject category)