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Sökning: onr:"swepub:oai:DiVA.org:ltu-73761" > Spring flood induce...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00005326naa a2200565 4500
001oai:DiVA.org:ltu-73761
003SwePub
008190425s2019 | |||||||||||000 ||eng|
009oai:portal.research.lu.se:publications/2bba2211-5e4e-486d-85de-f5d03e0c3c7d
0247 a https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-737612 URI
0247 a https://doi.org/10.1016/j.apgeochem.2019.1043852 DOI
0247 a oai:portal.research.lu.se:publications/2bba2211-5e4e-486d-85de-f5d03e0c3c7d2 URI
040 a (SwePub)ltud (SwePub)lu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
1001 a Herzog, Simon D.u Department of Science and Environment, Roskilde University, Roskilde, Denmark,Zealand University Hospital4 aut
2451 0a Spring flood induced shifts in Fe speciation and fate at increased salinity
264 1b Elsevier,c 2019
338 a print2 rdacarrier
500 a Validerad;2019;Nivå 2;2019-08-20 (johcin);Artikeln har tidigare förekommit som manuskript i avhandling.
520 a Rivers have traditionally been viewed as negligible sources of iron (Fe) to marine waters, as most Fe gets lost during estuarine mixing. However, recent findings demonstrate that Fe from boreal rivers display a higher resistance towards salinity-induced aggregation, presumably due to stabilizing interactions with organic matter. Previous studies have shown that Fe (oxy)hydroxides are selectively removed by aggregation processes, and that organic Fe complexes are less affected by increasing salinity. It has been further proposed that Fe speciation varies in response to seasonal differences in hydrology. In this study X-ray absorption spectroscopy (XAS) was used to determine the temporal variation in Fe speciation and the connection to Fe stability in response to increasing salinity in two boreal rivers (Kalix and Råne River), with the purpose to better understand the fate of riverine Fe export. Sampling was done from winter pre-flood, over the spring flood, to post-flood conditions (early April until mid June). In addition, parallel analyses for Fe speciation and isotope composition (δ56Fe relative to IRMM-14) were made on river samples, as well as salinity-induced aggregates and the fraction remaining in suspension, with the main objective to test if δ56Fe reflect the speciation of Fe.The contribution of organically complexed Fe increased during spring flood compared to the pre- and post-flood, as did Fe transport capacity. However, since Fe (oxy)hydroxides were dominating throughout the sampling period, the seasonal variability was small. Interestingly, salinity-induced aggregation experiments revealed that Fe (oxy)hydroxides, which dominated aggregates, displayed lower δ56Fe than in the river samples Fe, while organic Fe complexes in suspension had higher δ56Fe values. The seasonal variability in Fe isotope signature could not be simply linked to Fe speciation, but was probably also influenced by variation in source areas of Fe and processes along the flow-path that alter both Fe speciation and isotopic composition.
650 7a NATURVETENSKAPx Geovetenskap och relaterad miljövetenskapx Geokemi0 (SwePub)105062 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciencesx Geochemistry0 (SwePub)105062 hsv//eng
650 7a NATURVETENSKAPx Geovetenskap och relaterad miljövetenskapx Oceanografi, hydrologi och vattenresurser0 (SwePub)105092 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciencesx Oceanography, Hydrology and Water Resources0 (SwePub)105092 hsv//eng
653 a Fe geochemistry
653 a Fe speciation
653 a Fe isotopes
653 a Organically complexed Fe
653 a Fe (oxy)hydroxides
653 a Boreal
653 a Sub-arctic
653 a Transport capacity
653 a Salinity gradient
653 a XAS
653 a Tillämpad geokemi
653 a Applied Geochemistry
7001 a Conrad, Sarahu Luleå tekniska universitet,Geovetenskap och miljöteknik,Applied Geochemistry,Luleå University of Technology4 aut0 (Swepub:ltu)sarcon
7001 a Ingri, Johanu Luleå tekniska universitet,Geovetenskap och miljöteknik,Applied Geochemistry,Luleå University of Technology4 aut0 (Swepub:ltu)join
7001 a Persson, Peru Centre for Environmental and Climate Research & Department of Biology, Lund University, Lund, Sweden,Centre for Environmental and Climate Science (CEC),Centrum för miljö- och klimatvetenskap (CEC)4 aut0 (Swepub:lu)ca05969a-f748-4577-a918-51f43655bce1
7001 a Kritzberg, Emma S.u Lund University4 aut0 (Swepub:lu)12e1c266-067d-499d-96b2-c857b5ccef73
7102 a Department of Science and Environment, Roskilde University, Roskilde, Denmarkb Zealand University Hospital4 org
7730 t Applied Geochemistryd : Elsevierg 109q 109x 0883-2927x 1872-9134
8564 u https://doi.org/10.1016/j.apgeochem.2019.104385
8564 u https://doi.org/10.1016/j.apgeochem.2019.104385x freey FULLTEXT
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-73761
8564 8u https://doi.org/10.1016/j.apgeochem.2019.104385
8564 8u oai:portal.research.lu.se:publications/2bba2211-5e4e-486d-85de-f5d03e0c3c7d

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