| 1. |
- Chen, Zhe, et al.
(författare)
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Nano-scale characterization of white layer in broached Inconel 718
- 2017
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Ingår i: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
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Tidskriftsartikel (refereegranskat)abstract
- The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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| 2. |
- Grolig, Jan Gustav, 1986
(författare)
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Coated Ferritic Stainless Steels as Interconnects in Solid Oxide Fuel Cells - Material Development and Electrical Properties
- 2015
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Solid oxide fuel cells (SOFCs) are attracting increasing interest as devices with potentialuses in decentralized and clean electricity and heat production. Several challengeswith respect to materials have to be overcome to achieve efficiencies and life-spansthat are sufficient for long-term applications.An important element of an SOFC stack is the interconnect component, which connectstwo adjacent fuel cell elements. Interconnects, which are commonly composedof ferritic stainless steels, have to be corrosion-resistant, mechanically stable and costoptimized.This work aimed to investigate economic solutions for interconnect materials and tounderstand the underlying mechanisms of degradation and electrical conduction ofthese materials. Mainly two substrates, a commercially available steel (AISI 441) anda ferritic stainless steel that was optimized for an SOFC application (Sandvik SanergyHT) were combined with different barrier coatings and exposed to a cathode-sideatmosphere. A method was developed that allows for the electrical characterizationof promising material systems and model alloys, thereby facilitating a fundamentalunderstanding of the dominant electrical conduction processes linked to the oxidescales that grow on interconnects. The AISI 441 steel coated with reactive elementsand cobalt showed good corrosion and chromium evaporation profiles, while AISI 441coated with cerium and cobalt also had promising electrical properties. The SanergyHT steel was examined with coatings of copper and iron and copper and manganese,respectively. The corrosion and chromium evaporation profiles of Sanergy HT wereimproved by coating with copper and iron. The copper and iron-coated Sanergy HTshowed lower area specific resistance values than cobalt-coated Sanergy HT. Chromia,which is the main constituent of oxide scales, was synthesized using differentmethods. The electrical properties of chromia were found to be sensitive to not onlyimpurities, but also heat treatment. Finally the electrical properties of cobalt- andcobalt cerium-coated Sanergy HT steels were investigated. It was revealed that theaddition of cerium improved the conductivity of the interconnect by both slowingdown chromia growth and preventing the outward diffusion of iron into the spinel.
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| 3. |
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| 4. |
- Stolen, Reidar, et al.
(författare)
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Solcelleteknologi og brannsikkerhet
- 2018
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Bruken av solcelleteknologi er i stor vekst i Norge. I denne studien er branntekniske utfordringer ved bruk av solcelleteknologi undersøkt, med hensyn på brannstart, brannspredning og brannslokking. Studien danner et kunnskapsgrunnlag for å ivareta brannsikkerheten under montering, drift og under slokkeinnsats, samt for å utforme et enhetlig og tydelig regelverk. Resultatene fra studien viser:Brannstart: Solcelleinstallasjoner inneholder mange koblingspunkt, som kan være potensielle tennkilder, og en liten mengde brennbare materialer. Dermed er det som trengs til stede for å starte en brann. Det er viktig at alle kontaktpunkter i solcelleinstallasjonen er robuste og tåler den påkjenningen de blir utsatt for gjennom sin levetid uten at det oppstår dårlig kontakt som kan føre til brann.Brannspredning: For utenpåmonterte solcellemoduler er det ofte en åpen luftspalte mellom modul og bygning. Dersom det er en brann i denne luftspalten, vil varmen kunne bli akkumulert, noe som kan føre til raskere og større brannspredning enn om bygningsoverflaten ikke hadde vært tildekket. I fullskalaforsøk med solcellemoduler montert på tak spredte brannen seg under hele arealet som var dekket av moduler, men stoppet da den nærmet seg kanten av dette arealet. Dette illustrerer viktigheten av at områder med solceller utenpå en bygning blir seksjonert for å unngå brannspredning. Eventuelt kan det benyttes mindre brennbare materialer på taket under solcellemodulene for å motvirke den økte varmepåkjenningen som solcellemodulene gir. Luftspalten mellom modul og bygning kan potensielt også gi endringer i luftstrømningen langs bygget, som igjen kan påvirke brannspredningen.Brannslokking: Brannvesenet har behov for informasjon om det er solcelleinstallasjon i bygget og hvilke deler av det elektriske anlegget som kan være spenningssatt. Under slokkeinnsats må brannvesenet ta hensyn til berøringsfare, og fare for at det kan oppstå lysbuer og andre feil som kan føre til nye antennelsespunkt. Ferskvann kan brukes som slokkemiddel, dette må spyles fra minimum 1 meters avstand med spredt stråle og minimum 5 meters avstand med samlet stråle. Solcellemoduler kan komplisere brannslokking ved at de danner en fysisk barriere mellom brannvesenet og brannen, samt fordi det må tas hensyn til plassering av spenningssatte komponenter. Når disse punktene er tatt høyde for, bør ikke utenpåmonterte solcelleinstallasjoner være et problem.Videre arbeid: For utenpåmonterte solcelleinstallasjoner, er det lite forskning på vertikal montering (på fasader), og hvordan en eventuell endret branndynamikk kan påvirke brannspredning og slokking. Videre er det i dag økende bruk av bygningsintegrerte solcelleinstallasjoner, noe som gir mange mulige nye utfordringer for brannsikkerheten og for regelverk, ettersom solcellen da er en del av bygningskroppen, samtidig som den er en elektrisk komponent. Tysk statistikk tyder på at brannrisiko for slike installasjoner kan være større enn for utenpåmonterte solcelleinstallasjoner, og dette vil det derfor være viktig å undersøke nærmere.
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| 5. |
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| 6. |
- Skagestad, Ragnhild, 1978, et al.
(författare)
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GCCSI Webinar: Cutting Cost of CO2 Capture in Process Industry (CO2stCap) Project overview & first results for partial CO2 capture at integrated steelworks
- 2017
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- GCCSI Webinar: Cutting Cost of CO2 Capture in Process Industry (CO2stCap) Project overview & first results for partial CO2 capture at integrated steelworks This publication has the format of a webinar: The CO2StCap project is a four year initiative carried out by industry and academic partners with the aim of reducing capture costs from CO2 intensive industries (more information here). The project, led by Tel-Tek, is based on the idea that cost reduction is possible by capturing only a share of the CO2 emissions from a given facility, instead of striving for maximized capture rates. This can be done in multiple ways, for instance by capturing only from the largest CO2 sources at individual multi-stack sites utilising cheap waste heat or adapting the capture volumes to seasonal changes in operations. The main focus of this research is to perform techno-economic analyses for multiple partial CO2 capture concepts in order to identify economic optimums between cost and volumes captured. In total for four different case studies are developed for cement, iron & steel, pulp & paper and ferroalloys industries. The first part of the webinar gave an overview of the project with insights into the cost estimation method used. The second part presented the iron & steel industry case study based on the Lulea site in Sweden, for which waste-heat mapping methodology has been used to assess the potential for partial capture via MEA-absorption. Capture costs for different CO2 sources were discussed, demonstrating the viability of partial capture in an integrated steelworks.
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| 7. |
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| 8. |
- Hosseini Bab Anari, Elham, 1982, et al.
(författare)
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Fluorine-free salts for aqueous lithium-ion and sodium-ion battery electrolytes
- 2016
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Ingår i: RSC Advances. - : Royal Society of Chemistry (RSC). - 2046-2069. ; 6:88, s. 6, 85194-85201
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Tidskriftsartikel (refereegranskat)abstract
- A first generation of fluorine-free lithium and sodium salts based on the concept of pseudo-delocalized anions has been synthesized with both high purity and yield using water as the solvent in the reaction medium. The salts have been fully characterized by Raman and FT-IR spectroscopies, thermogravimetry, and X-ray crystallography to reveal both basic properties in terms of thermal stability and solubility as well as the local, mainly ion–ion interaction dictated, coordination details and by ionic conductivity and electrochemical stability window measurements as aqueous electrolytes. Together a picture is created of the salts' promise as components in electrolytes – primarily aiming at application in low voltage fluorinefree aqueous lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs).
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| 9. |
- Heshmati, Mohsen, 1987, et al.
(författare)
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On the strength prediction of adhesively bonded FRP-steel joints using cohesive zone modelling
- 2018
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Ingår i: Theoretical and applied fracture mechanics (Print). - : Elsevier BV. - 0167-8442 .- 1872-7638. ; 93, s. 64-78
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Tidskriftsartikel (refereegranskat)abstract
- The variety of failure modes that are likely to occur in fibre-reinforced polymer (FRP)/steel joints used in the construction industry adds to the complexity associated with the design of these joints. This variation in possible failure modes is mainly attributed to the lack of a controlled application environment and to rather insufficient quality assurance protocols and procedures. The use of energy-based methods such as, cohesive zone modelling (CZM), can be a solution to circumvent such complexities. This paper investigates a number of issues related to CZM analyses of FRP/steel adhesive joints using various test configurations and a comprehensive numerical study. Parameters such as the effect of shape and type of cohesive law, crack path location, length of damage process zone, variations of adhesive and FRP properties, and different failure modes including cohesive, interfacial debonding and FRP failure on the strength of joints are investigated. The results show that the behaviour of the tested joints is accurately predicted provided that the variation of failure modes are taken into account. Moreover, it is shown that the damage process zone in adhesive layer is directly proportional to the shape of cohesive laws. This feature can be employed in the design phase to ensure sufficient overlap length and to account for important in-service parameters such as temperature and moisture.
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| 10. |
- Lei, Yu, et al.
(författare)
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Graphene and Beyond: Recent Advances in Two-Dimensional Materials Synthesis, Properties, and Devices
- 2022
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Ingår i: ACS Nanoscience Au. - : American Chemical Society (ACS). - 2694-2496. ; 2:6, s. 450-485
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Forskningsöversikt (refereegranskat)abstract
- Since the isolation of graphene in 2004, two-dimensional (2D) materials research has rapidly evolved into an entire subdiscipline in the physical sciences with a wide range of emergent applications. The unique 2D structure offers an open canvas to tailor and functionalize 2D materials through layer number, defects, morphology, moiré pattern, strain, and other control knobs. Through this review, we aim to highlight the most recent discoveries in the following topics: theory-guided synthesis for enhanced control of 2D morphologies, quality, yield, as well as insights toward novel 2D materials; defect engineering to control and understand the role of various defects, including in situ and ex situ methods; and properties and applications that are related to moiré engineering, strain engineering, and artificial intelligence. Finally, we also provide our perspective on the challenges and opportunities in this fascinating field.
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