| 1. |
- Chen, Zhe, et al.
(författare)
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Nano-scale characterization of white layer in broached Inconel 718
- 2017
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Ingår i: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
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Tidskriftsartikel (refereegranskat)abstract
- The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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| 2. |
- Eivazihollagh, Alireza, et al.
(författare)
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On chelating surfactants : Molecular perspectives and application prospects
- 2019
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Ingår i: Journal of Molecular Liquids. - : Elsevier BV. - 0167-7322 .- 1873-3166. ; 278, s. 688-705
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Tidskriftsartikel (refereegranskat)abstract
- Chelating agents, molecules that very strongly coordinates certain metal ions, are used industrially as well as in consumer products to minimize disturbances and increase performance of reactions and applications. The widely used sequestering agents, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) belong to this branch of readily water-soluble compounds. When these chemical structures also have hydrophobic parts, they are prone to adsorb at air-water interfaces and to self-assemble. Such bifunctional molecules can be called chelating surfactants and will have more extended utilization prospects than common chelating agents or ordinary ionic surfactants. The present review attempts to highlight the fundamental behavior of chelating surfactants in solution and at interfaces, and their very specific interactions with metal ions. Methods to recover chelating surfactants from metal chelates are also described. Moreover, utilization of chelating surfactants in applications for metal removal in environmental engineering and mineral processing, as well as for metal control in the fields of biology, chemistry and physics, is exemplified and discussed.
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| 3. |
- Decrop, Deborah, et al.
(författare)
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Single-step manufacturing of femtoliter microwell arrays in a novel surface energy mimicking polymer
- 2015
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Ingår i: 18th International Conference on Solid-State Sensors, Actuators and Microsystems (IEEE TRANSDUCER 2015). - : IEEE.
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Konferensbidrag (refereegranskat)abstract
- We report a novel polymer material formulation and stamp-molding technique that enable rapid single-step manufacturing of hydrophilic-in-hydrophobic microwell arrays. We developed a modified thiol-ene-epoxy polymer (mOSTE+) formulation that mimics the surface energy of its mold during polymerization. The polymer inherits the surface energy from the mold through molecular self-assembly, in which functional monomers self-assemble at the interface between the liquid prepolymer and the mold surface. Combining this novel mOSTE+ material with a stamp-molding process leads to simultaneous surface energy mimicking and micro-structuring. This method was used to manufacture microwells with hydrophilic bottom and hydrophobic sidewall, depressed in a surrounding hydrophobic surface. The microwell arrays were successfully tested for the self-assembly of 62’000 femtoliter-droplets. Such femtoliter droplet arrays are useful for, e.g., digital ELISA and single cell/molecule analysis applications.
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| 4. |
- Pardon, Gaspard, 1983-
(författare)
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From Macro to Nano : Electrokinetic Transport and Surface Control
- 2014
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Today, the growing and aging population, and the rise of new global threats on human health puts an increasing demand on the healthcare system and calls for preventive actions. To make existing medical treatments more efficient and widely accessible and to prevent the emergence of new threats such as drug-resistant bacteria, improved diagnostic technologies are needed. Potential solutions to address these medical challenges could come from the development of novel lab-on-chip (LoC) for point-of-care (PoC) diagnostics.At the same time, the increasing demand for sustainable energy calls for the development of novel approaches for energy conversion and storage systems (ECS), to which micro- and nanotechnologies could also contribute.This thesis has for objective to contribute to these developments and presents the results of interdisciplinary research at the crossing of three disciplines of physics and engineering: electrokinetic transport in fluids, manufacturing of micro- and nanofluidic systems, and surface control and modification. By combining knowledge from each of these disciplines, novel solutions and functionalities were developed at the macro-, micro- and nanoscale, towards applications in PoC diagnostics and ECS systems.At the macroscale, electrokinetic transport was applied to the development of a novel PoC sampler for the efficient capture of exhaled breath aerosol onto a microfluidic platform.At the microscale, several methods for polymer micromanufacturing and surface modification were developed. Using direct photolithography in off-stoichiometry thiol-ene (OSTE) polymers, a novel manufacturing method for mold-free rapid prototyping of microfluidic devices was developed. An investigation of the photolithography of OSTE polymers revealed that a novel photopatterning mechanism arises from the off-stoichiometric polymer formulation. Using photografting on OSTE surfaces, a novel surface modification method was developed for the photopatterning of the surface energy. Finally, a novel method was developed for single-step microstructuring and micropatterning of surface energy, using a molecular self-alignment process resulting in spontaneous mimicking, in the replica, of the surface energy of the mold.At the nanoscale, several solutions for the study of electrokinetic transport toward selective biofiltration and energy conversion were developed. A novel, comprehensive model was developed for electrostatic gating of the electrokinetic transport in nanofluidics. A novel method for the manufacturing of electrostatically-gated nanofluidic membranes was developed, using atomic layer deposition (ALD) in deep anodic alumina oxide (AAO) nanopores. Finally, a preliminary investigation of the nanopatterning of OSTE polymers was performed for the manufacturing of polymer nanofluidic devices.
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| 5. |
- Fu, Qilin, 1986-
(författare)
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High dynamic stiffness nano-structured composites for vibration control : A Study of applications in joint interfaces and machining systems
- 2015
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Vibration control requires high dynamic stiffness in mechanical structures for a reliable performance under extreme conditions. Dynamic stiffness composes the parameters of stiffness (K) and damping (η) that are usually in a trade-off relationship. This thesis study aims to break the trade-off relationship.After identifying the underlying mechanism of damping in composite materials and joint interfaces, this thesis studies the deposition technique and physical characteristics of nano-structured HDS (high dynamic stiffness) composite thick-layer coatings. The HDS composite were created by enlarging the internal grain boundary surface area through reduced grain size in nano scale (≤ 40 nm). The deposition process utilizes a PECVD (Plasma Enhanced Chemical Vapour Deposition) method combined with the HiPIMS (High Power Impulse Magnetron Sputtering) technology. The HDS composite exhibited significantly higher surface hardness and higher elastic modulus compared to Poly(methyl methacrylate) (PMMA), yet similar damping property. The HDS composites successfully realized vibration control of cutting tools while applied in their clamping interfaces.Compression preload at essential joint interfaces was found to play a major role in stability of cutting processes and a method was provided for characterizing joint interface properties directly on assembled structures. The detailed analysis of a build-up structure showed that the vibrational mode energy is shifted by varying the joint interface’s compression preload. In a build-up structure, the location shift of vibration mode’s strain energy affects the dynamic responses together with the stiffness and damping properties of joint interfaces.The thesis demonstrates that it is possible to achieve high stiffness and high damping simultaneously in materials and structures. Analysis of the vibrational strain energy distribution was found essential for the success of vibration control.
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| 6. |
- Banuazizi, Seyed Amir Hossein
(författare)
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Determining and Optimizing the Current and Magnetic Field Dependence of Spin-Torque and Spin Hall Nano-Oscillators : Toward Next-Generation Nanoelectronic Devices and Systems
- 2018
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Spin-torque and spin Hall nano-oscillators are nanoscale devices (about 100 nm) capable of producing tunable broadband high-frequency microwave signals ranging from 0.1 GHz to over 65 GHz that several research groups trying to reach up to 200 - 300 GHz. Their development is ongoing for applications in high-frequency nanoelectronic devices and systems, such as mobile phones, wireless networks, base stations, vehicle radars, and even medical applications.This thesis covers a wide range of characterizations of spin-torque and spin Hall nano-oscillator devices that aim to investigate their current and magnetic field dependency, as well as to suggest improvements in these devices to optimize their application in spintronics and magnonics. The work is primarily based on experimental methods for characterizing these devices by building up new measurement systems, but it also includes numerical and micromagnetic simulations.Experimental techniques: In order to characterize the fabricated nanodevices in a detailed and accurate manner through their electrical and microwave responses, new measurement systems capable of full 3D control over the external magnetic fields will be described. In addition, a new method of probing an operational device using magnetic force microscopy (MFM) will be presented.Spin-torque nano-oscillators: We will describe remarkable improvements in the performance of spin-torque nano-oscillators (STNOs) that enhance their integration capability with applications in microwave systems. In nanocontact (NC-)STNOs made from a conventional spin-valve stack, though with thicker bottom electrodes, it is found the auto-oscillations can be excited with higher frequencies at lower threshold currents, and with higher output powers. We also find that this idea is useful for tuning spin-wave resonance and also controlling the thermal budget. Furthermore, a detailed study of magnetic droplet solitons and spin-wave dynamics in NC-STNOs will be described. Finally, we demonstrate ultra-high frequency tunability in low-current STNOs based on perpendicular magnetic tunnel junctions(p-MTJs).Spin Hall nano-oscillators: Characterizations of spin Hall nano-oscillator(SHNO) devices based on different structures and materials with both conventional and novel methods will be described. A detailed study of the current, temperature, and magnetic field profiles of nanogap SHNOs will be presented. In addition, we show the current and magnetic field dependence of nanoconstriction-based SHNOs.Moreover, it is shown that multiple SHNOs can be serially synchronized, thereby increasing their output power and enhancing the usage of these devices in applications such as neuromorphic computing. We show synchronization of multiple nanoconstriction SHNOs in the presence of a low in-plane magnetic field. Finally, there is a demonstration of the results of a novel method for probing an operationalSHNO using MFM.
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| 7. |
- Mellin, Pelle, 1985-, et al.
(författare)
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Nano-sized by-products from metal 3D printing, composite manufacturing and fabric production
- 2016
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Ingår i: Journal of Cleaner Production. - Sweden : Elsevier. - 0959-6526 .- 1879-1786. ; 139, s. 1224-1233
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Tidskriftsartikel (refereegranskat)abstract
- Recently, the health and environmental perspective of nano-materials has gained attention. Most previous work focused on Engineered Nanoparticles (ENP). This paper examines some recently introduced production routes in terms of generated nano-sized by-products. A discussion on the hazards of emitting such particles and fibers is included. Fine by-products were found in recycled metal powder after 3D printing by Selective Laser Melting (SLM). The process somehow generated small round metal particles (~1e2 mm) that are possibly carcinogenic and respirable, but not small enough to enter by skin-absorption. With preventive measures like closed handling and masks, any health related effects can be prevented. The composite manufacturing in particular generated ceramic and carbonaceous particles that are very small and respirable but do not appear to be intrinsically toxic. The smallest features in agglomerates were about 30 nm. Small particles and fibers that were not attached in agglomerates were found in a wide range of sizes, from 1 μm and upwards. Preventive measures like closed handling and masks are strongly recommended. In contrast, the more traditional production route of fabric production is investigated. Here, brushing residue and recycled wool from fabric production contained few nano-sized by-products.
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| 8. |
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| 9. |
- Sepehri, Sobhan, 1986, et al.
(författare)
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Volume-amplified magnetic bioassay integrated with microfluidic sample handling and high-Tc SQUID magnetic readout
- 2018
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Ingår i: APL Bioengineering. - : AIP Publishing. - 2473-2877. ; 2:1
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Tidskriftsartikel (refereegranskat)abstract
- A bioassay based on a high-Tc superconducting quantum interference device (SQUID) reading out functionalized magnetic nanoparticles (fMNPs) in a prototype microfluidic platform is presented. The target molecule recognition is based on volume amplification using padlock-probe-ligation followed by rolling circle amplification (RCA). The MNPs are functionalized with single-stranded oligonucleotides, which give a specific binding of the MNPs to the large RCA coil product, resulting in a large change in the amplitude of the imaginary part of the ac magnetic susceptibility. The RCA products from amplification of synthetic Vibrio cholera target DNA were investigated using our SQUID ac susceptibility system in microfluidic channel with an equivalent sample volume of 3 μl. From extrapolation of the linear dependence of the SQUID signal versus concentration of the RCA coils, it is found that the projected limit of detection for our system is about 1.0 e5 RCA coils (0.2e−18 mol), which is equivalent to 66 fM in the 3 μl sample volume. This ultra-high magnetic sensitivity and integration with microfluidic sample handling are critical steps towards magnetic bioassays for rapid detection of DNA and RNA targets at the point of care.
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| 10. |
- Grabowski, Alexander, 1993
(författare)
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VCSEL Equivalent Circuits and Silicon Photonics Integration
- 2022
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The vertical-cavity surface-emitting laser (VCSEL) is a light source of great importance for numerous industrial and consumer products. The main application areas are datacom and sensing. The datacom industry uses GaAs-based VCSELs for optical interconnects, the short-reach fiber optical communication links used to transfer large amounts of data at high rates between units within data centers and supercomputers. In the area of sensing, VCSELs are largely used in consumer products such as smart phones (e.g. face ID and camera auto focus), computer mice, and automobiles (e.g. gesture recognition and LIDAR for autonomous driving). In this work, an advanced physics-based equivalent circuit model for datacom VCSELs has been developed. The model lends itself to co-design and co-optimization with driver and receiver ICs, thereby enabling higher data rate transceivers with bandwidth limited VCSELs and photodiodes. The model also facilitates an understanding of how each physical process within the VCSEL affects the VCSEL static and dynamic performance. It has been applied to study the impact of carrier transport and capture on VCSEL dynamics. The work also includes micro-transfer-printing of GaAs-based single-mode VCSELs on silicon nitride photonic integrated circuits (PICs). Such PICs are increasingly used for e.g. compact and highly functional bio-photonic sensors. Transfer printing of VCSELs enables the much-needed on-PIC integration of power efficient light sources. The bottom-emitting VCSELs are printed above grating couplers on the PIC and optical feedback is used to control the polarization for efficient coupling to the silicon nitride waveguide. Wavelength tuning, as required by the bio-sensing application, is achieved by direct current modulation.
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