| 1. |
- Bozkurt, S., et al.
(author)
-
Peat as a potential analogue for the long-term evolution in landfills
- 2001
-
In: Earth-Science Reviews. - 0012-8252 .- 1872-6828. ; 53:02-jan, s. 95-147
-
Research review (peer-reviewed)abstract
- A survey of the existing studies on peat and its decomposition processes is presented with the aim to characterise the long-term behaviour of peat accumulating systems. The chemical and physical characteristics of peat together with its accumulation and decay processes have been analysed. Peat is an acidic mixture of dead and decomposed. mainly vegetable, matter formed in boggy areas; it is the youngest and least altered component of the combustible rocks and is characterised by the lowest content of fixed carbon and the highest content of volatile constituents. Peat is formed by degeneration processes under exclusion of atmospheric oxygen by the action of water; the speed of formation depends upon the climatic and environmental conditions. In most peatlands two layers can be characterised: the aerobic acrotelm and the anaerobic catotelm, their relative importance being controlled mainly by the position of the water table. In the acrotelm the aerobic processes are responsible for the loss of up to 90% of the original mass, Degeneration in the acidic and anaerobic catotelm is still imperfectly characterised even though the catotelm is the real site of peat accumulation. Most of the recent literature considers peat as composed of easily degradable compounds, e.g. polysaccharides. and recalcitrant matter (lignin and complex aromatics). The lone-term destiny of peat has not been sufficiently characterised: although in a large majority of cases it seems probable that peat decomposes completely (even though slowly) provided that it is given a sufficiently long residence rime in the catotelm, some cases can still be interpreted as examples of simple accumulation. The rates of influx of oxygen and hence the degradation of organic matter into both saturated and partially saturated peat have been estimated. The depletion rate is about 4500 g m(-1) year(-1) for partially saturated peat. The average depletion rate of the peat for this case will then be such that it will take on the order of 5 to 50 years to degrade half of the organics in a 10 cm partially saturated layer. For the water-saturated case the depletion rate varies between 8 and 12 g m(-2) year(-1), which is considerably lower than in the partially saturated region. The models used to analyse the field and laboratory data on generation, diffusion and emission of methane and carbon dioxide indicate that laboratory data and field observations agree reasonably well. It is suggested that peat-accumulating ecosystems may be valuable natural analogues for the study of the long-term destiny of industrial and municipal solid wastes. Accurate studies of active mires together with an ad hoc review of the existing literature give valuable insights in this problem. Peatlands might then be considered as organic waste deposition experiments lasting up to several thousands years.
|
|
| 2. |
- Ledin, Maria
(author)
-
Accumulation of metals by microorganisms : processes and importance for soil systems
- 2000
-
In: Earth-Science Reviews. - 0012-8252 .- 1872-6828. ; 51:1-4, s. 1-31
-
Journal article (peer-reviewed)abstract
- Metal accumulation by solid substances can counteract metal mobilization in the environment if the solid substance is immobile. Microorganisms have a high surface area-to-volume ratio because of their small size and therefore provide a large contact area that can interact with metals in the surrounding environment. Microbial metal accumulation has received much attention in the last years due to the potential use of microorganisms for cleaning metal-polluted water. However, considerably less attention has been paid to the role of microorganisms for metal mobility in soil even though the same processes may occur there. Therefore, this paper highlights this area. The different accumulation processes that microorganisms perform are analyzed and their potential significance in soil systems is discussed. Different kinds of mechanisms can be involved in the accumulation of metals by microorganisms, e.g. adsorption, precipitation, complexation and active transport into the cell. Physicochemical parameters like pH and ionic composition, as well as biological factors are of importance for the magnitude of accumulation. Often large amounts of metals can be accumulated with varying specificity, and microorganisms may provide nucleation sites for mineral formation. Several studies of microbial metal accumulation have been made with different methods and aims. Most of these studies concern single-component systems with one organism at a time. Data from accumulation experiments with pure cultures of microorganisms have been used to model the overall metal retention in soil. A further development is experimental model systems using various solid soil components in salt medium. Microbial metal accumulation is difficult to study in situ, but some experimental methods have been applied as tools for studying real soil systems, e.g. litter bags buried in soil containing microorganisms, a method where discs with microorganisms have been put onto agar plates with soil extracts, and comparison of sterilized and non-sterilized soils or soils with or without nutrient amendment. Different aspects of microbial metal accumulation are emphasized with the different methods applied. Single-component systems have the advantage of providing excellent information of the metal binding properties of microorganisms but cannot directly be applied to metal behavior in the heterogenous systems that real soils constitute. Studies focused on the behavior of metals in real soils can, in contrast, provide information on the overall metal distribution but less insight into the processes involved. Obviously, a combination of approaches is needed to describe metal distribution and mobility in polluted soil such as areas around mines. Different kinds of multi-component systems as well as modelling may bridge the gap between these two types of studies. Several experimental methods, complementary to each other and designed to allow for comparison, may emphasize different aspects of metal accumulation and should therefore be considered. To summarize, there are studies that indicate that microorganisms may also accumulate metals in soil and that the amounts may be considerable. However, much work remains to be done, with the focus of microorganisms in soil. It is also important to put microbial metal accumulation in relation to other microbial processes in soil, which can influence metal mobility, to determine the overall influence of soil microorganisms on metal mobility, and to be able to quantify these processes.
|
|
| 3. |
- Abbott, Benjamin, et al.
(author)
-
Using multi-tracer inference to move beyond single-catchment ecohydrology
- 2016
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 160, s. 19-42
-
Journal article (peer-reviewed)abstract
- Protecting or restoring aquatic ecosystems in the face of growing anthropogenic pressures requires an understanding of hydrological and biogeochemical functioning across multiple spatial and temporal scales. Recent technological and methodological advances have vastly increased the number and diversity of hydrological, biogeochemical, and ecological tracers available, providing potentially powerful tools to improve understanding of fundamental problems in ecohydrology, notably: 1. Identifying spatially explicit flowpaths, 2. Quantifying water residence time, and 3. Quantifying and localizing biogeochemical transformation. In this review, we synthesize the history of hydrological and biogeochemical theory, summarize modem tracer methods, and discuss how improved understanding of flowpath, residence time, and biogeochemical transformation can help ecohydrology move beyond description of site-specific heterogeneity. We focus on using multiple tracers with contrasting characteristics (crossing proxies) to infer ecosystem functioning across multiple scales. Specifically, we present how crossed proxies could test recent ecohydrological theory, combining the concepts of hotspots and hot moments with the Damkohler number in what we call the HotDam framework.
|
|
| 4. |
- Akam, Sajjad A., et al.
(author)
-
Methane-derived authigenic carbonates – A case for a globally relevant marine carbonate factory
- 2023
-
In: Earth-Science Reviews. - 0012-8252 .- 1872-6828. ; 243
-
Journal article (peer-reviewed)abstract
- Precipitation of methane-derived authigenic carbonates (MDAC) is an integral part of marine methane production and consumption, but MDAC's relative significance to the global marine carbon cycle is not well understood. Here we provide a synthesis and perspective to highlight MDAC from a global marine carbon biogeochemistry viewpoint. MDAC formation is a result and archive of carbon‑sulfur (C S) coupling in the shallow sulfatic zone and carbon‑silicon (C Si) coupling in deeper methanic sediments. MDAC constitute a carbon sequestration of 3.93 Tmol C yr−1 (range 2.34–5.8 Tmol C yr−1) in the modern ocean and are the third-largest carbon burial mechanism in marine sediments. This burial compares to 29% (11–57%) organic carbon and 10% (6–23%) skeletal carbonate carbon burial along continental margins. MDAC formation is also an important sink for benthic alkalinity and, thereby, a potential contributor to bottom water acidification. Our understanding of the impact of MDAC on global biogeochemical cycles has evolved over the past five decades from what was traditionally considered a passive carbon sequestration mechanism in a seep-oasis setting to what is now considered a dynamic carbonate factory expanding from deep sediments to bottom waters—a factory that has been operational since the Precambrian. We present a strong case for the need to improve regional scale quantification of MDAC accumulation rates and associated carbonate biogeochemical parameters, leading to their incorporation in present and paleo‑carbon budgets in the next phase of MDAC exploration.
|
|
| 5. |
- Bagherbandi, Mohammad, et al.
(author)
-
A new Fennoscandian crustal thickness model based on CRUST1.0 and a gravimetric-isostatic approach
- 2015
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 145, s. 132-145
-
Research review (peer-reviewed)abstract
- In this paper a new gravimetric-isostatic crustal thickness model (VMM14_FEN) is estimated for Fennoscandia. The main motivation is to investigate the relations between geological and geophysical properties, the Moho depth and crust-mantle density contrast at the crust-mantle discontinuity. For this purpose the Bouguer gravity disturbance data is corrected in two main ways namely for the gravitational contributions of mass density variation due to the different layers of the Earth's crust such as ice and sediments, as well as for the gravitational contribution from deeper masses below the crust. This second correction (for non-isostatic effects) is necessary because in general the crust is not in complete isostatic equilibrium and the observed gravity data are not only generated by the topographic/isostatic masses but also from those in the deep Earth interior. The correction for non-isostatic effects is mainly attributed to unmodeled mantle and core boundary density heterogeneities. These corrections are determined using the recent seismic crustal thickness model CRUST1.0. We compare our modeling results with previous studies in the area and test the fitness. The comparison with the external Moho model EuCRUST-07 shows a 3.3. km RMS agreement for the Moho depth in Fennoscandia. We also illustrate how the above corrections improve the Moho depth estimation. Finally, the signatures of geological structures and isostatic equilibrium are studied using VMM14_FEN, showing how main geological unit structures attribute in isostatic balance by affecting the Moho geometry. The main geological features are also discussed in the context of the complete and incomplete isostatic equilibrium.
|
|
| 6. |
- Bagherbandi, Mohammad, et al.
(author)
-
Improving gravimetric-isostatic models of crustal depth by correcting for non-isostatic effects and using CRUST2.0
- 2013
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 117, s. 29-39
-
Journal article (peer-reviewed)abstract
- The principle of isostasy is important in different fields of geosciences. Using an isostatic hypothesis for estimating the crustal thickness suffers from the more or less incomplete isostatic model and that the observed gravity anomaly is not only generated by the topographic/isostatic signal but also by non-isostatic effects (NIEs). In most applications of isostatic models the NIEs are disregarded. In this paper, we study how some isostatic models related with Vening Meinez's isostatic hypothesis can be improved by considering the NIE. The isostatic gravity anomaly needs a correction for the NIEs, which varies from as much as 494 mGal to -308 mGal. The result shows that by adding this correction the global crustal thickness estimate improves about 50% with respect to the global model CRUST2.0, i.e. the root mean square differences of the crustal thickness of the best Vening Meinesz type and CRUST2.0 models are 6.9 and 3.2 km before and after improvement, respectively. As a result, a new global model of crustal thickness using Vening Meinesz and CRUST2.0 models is generated. A comparison with an independent African crustal depth model shows an improvement of the new model by 6.8 km vs. CRUST2.0 (i.e. rms differences of 3.0 and 9.8 km, respectively). A comparison between oceanic lithosphere age and the NIEs is discussed in this study, too. One application of this study can be to improve crustal depth in areas where CRUST2.0 data are sparse and bad and to densify the resolution vs. the CRUST2.0 model. Other applications can be used to infer the viscosity of the mantle from the NIEs signal to study various locations around the Earth for understanding complete, over- and under-compensations of the topography.
|
|
| 7. |
- Baker, Paul A., et al.
(author)
-
The emerging field of geogenomics : Constraining geological problems with genetic data
- 2014
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 135, s. 38-47
-
Journal article (peer-reviewed)abstract
- The development of a genomics-derived discipline within geology is timely, as a result of major advances in acquiring and processing geologically relevant genetic data. This paper articulates the emerging field of geogenomics, which involves the use of large-scale genetic data to constrain geological hypotheses. The paper introduces geogenomics and discusses how hypotheses can be addressed through collaboration between geologists and evolutionary biologists. As an example, geogenomic methods are applied to evaluate competing hypotheses regarding the timing of the Andean uplift, the closure of the Isthmus of Panama, the onset of trans-Amazon drainage, and Quaternary climate variation in the Neotropics.
|
|
| 8. |
- Berglund, Örjan
(author)
-
Digital mapping of peatlands - A critical review
- 2019
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 196
-
Research review (peer-reviewed)abstract
- Peatlands offer a series of ecosystem services including carbon storage, biomass production, and climate regulation. Climate change and rapid land use change are degrading peatlands, liberating their stored carbon (C) into the atmosphere. To conserve peatlands and help in realising the Paris Agreement, we need to understand their extent, status, and C stocks. However, current peatland knowledge is vague estimates of global peatland extent ranges from 1 to 4.6 million km(2), and C stock estimates vary between 113 and 612 Pg (or billion tonne C). This uncertainty mostly stems from the coarse spatial scale of global soil maps. In addition, most global peatland estimates are based on rough country inventories and reports that use outdated data. This review shows that digital mapping using field observations combined with remotely-sensed images and statistical models is an avenue to more accurately map peatlands and decrease this knowledge gap. We describe peat mapping experiences from 12 countries or regions and review 90 recent studies on peatland mapping. We found that interest in mapping peat information derived from satellite imageries and other digital mapping technologies is growing. Many studies have delineated peat extent using land cover from remote sensing, ecology, and environmental field studies, but rarely perform validation, and calculating the uncertainty of prediction is rare. This paper then reviews various proximal and remote sensing techniques that can be used to map peatlands. These include geophysical measurements (electromagnetic induction, resistivity measurement, and gamma radiometrics), radar sensing (SRTM, SAR), and optical images (Visible and Infrared). Peatland is better mapped when using more than one covariate, such as optical and radar products using nonlinear machine learning algorithms. The proliferation of satellite data available in an open-access format, availability of machine learning algorithms in an open-source computing environment, and high-performance computing facilities could enhance the way peatlands are mapped. Digital soil mapping allows us to map peat in a cost-effective, objective, and accurate manner. Securing peatlands for the future, and abating their contribution to atmospheric C levels, means digitally mapping them now.
|
|
| 9. |
- Bertrand, Sebastien, et al.
(author)
-
Inorganic geochemistry of lake sediments : a review of analytical techniques and guidelines for data interpretation
- 2024
-
In: Earth-Science Reviews. - : Elsevier. - 0012-8252 .- 1872-6828. ; 249
-
Research review (peer-reviewed)abstract
- Inorganic geochemistry is a powerful tool in paleolimnology. It has become one of the most commonly used techniques to analyze lake sediments, particularly due to the development and increasing availability of XRF core scanners during the last two decades. It allows for the reconstruction of the continuous processes that occur in lakes and their watersheds, and it is ideally suited to identify event deposits. How earth surface processes and limnological conditions are recorded in the inorganic geochemical composition of lake sediments is, however, relatively complex. Here, we review the main techniques used for the inorganic geochemical analysis of lake sediments and we offer guidance on sample preparation and instrument selection. We then summarize the best practices to process and interpret bulk inorganic geochemical data. In particular, we emphasize that log-ratio transformation is critical for the rigorous statistical analysis of geochemical datasets, whether they are obtained by XRF core scanning or more traditional techniques. In addition, we show that accurately interpreting inorganic geochemical data requires a sound understanding of the main components of the sediment (organic matter, biogenic silica, carbonates, lithogenic particles) and mineral assemblages. Finally, we provide a series of examples illustrating the potential and limits of inorganic geochemistry in paleolimnology. Although the examples presented in this paper focus on lake and fjord sediments, the principles presented here also apply to other sedimentary environments.
|
|
| 10. |
- Betts, Marissa, J., et al.
(author)
-
Early Cambrian chronostratigraphy and geochronology of South Australia
- 2018
-
In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252 .- 1872-6828. ; 185, s. 498-543
-
Journal article (peer-reviewed)abstract
- The most successful chronostratigraphic correlation methods enlist multiple proxies such as biostratigraphy and chemostratigraphy to constrain the timing of globally important bio- and geo-events. Here we present the first regional, high-resolution shelly fossil biostratigraphy integrated with δ13C chemostratigraphy (and corresponding δ18O data) from the traditional lower Cambrian (Terreneuvian and provisional Cambrian Series 2) of South Australia. The global ZHUCE, SHICE, positive excursions II and III and the CARE are captured in lower Cambrian successions from the Arrowie and Stansbury basins. The South Australian shelly fossil biostratigraphy has a consistent relationship with the δ13C results, bolstering interpretation, identification and correlation of the excursions. Positive excursion II straddles the boundary between the Kulparina rostrata and Micrina etheridgei zones, and the CARE straddles the boundary between the M. etheridgei and Dailyatia odyssei zones, peaking in the lower parts of the latter zone. New CA-TIMS zircon dates from the upper Hawker Group and Billy Creek Formation provide geochronologic calibration points for the upper D. odyssei Zone and corresponding chemostratigraphic curve, embedding the lower Cambrian successions from South Australia into a global chronostratigraphic context. This multi-proxy investigation demonstrates the power of integrated methods for developing regional biostratigraphic schemes and facilitating robust global correlation of lower Cambrian successions from South Australia (part of East Gondwana) with coeval terranes on other Cambrian palaeocontinents, including South and North China, Siberia, Laurentia, Avalonia and West Gondwana.
|
|
