1. |
- Abbas, Ghazanfar, et al.
(författare)
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Electrochemical study of nanostructured electrode for low-temperature solid oxide fuel cell (LTSOFC)
- 2014
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 0363-907X .- 1099-114X. ; 38:4, s. 518-523
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Tidskriftsartikel (refereegranskat)abstract
- Zn-based nanostructured Ba0.05Cu0.25Fe0.10Zn0.60O (BCFZ) oxide electrode material was synthesized by solid-state reaction for low-temperature solid oxide fuel cell. The cell was fabricated by sandwiching NK-CDC electrolyte between BCFZ electrodes by dry press technique, and its performance was assessed. The maximum power density of 741.87 mW-cm(-2) was achieved at 550 degrees C. The crystal structure and morphology were characterized by X-ray diffractometer (XRD) and SEM. The particle size was calculated to be 25 nm applying Scherer's formula from XRD data. Electronic conductivities were measured with the four-probe DC method under hydrogen and air atmosphere. AC Electrochemical Impedance Spectroscopy of the BCFZ oxide electrode was also measured in hydrogen atmosphere at 450 degrees C.
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2. |
- Abrahamsson, K, et al.
(författare)
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Application of heat pump systems for energy conservation in paper drying
- 1997
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Ingår i: International Journal of Energy Research. - 0363-907X. ; 21:7, s. 631-642
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Tidskriftsartikel (refereegranskat)abstract
- Drying is one of the most energy intensive and common operations in the chemical and process industries. Scope for energy recovery is substantial, particularly from the latent heat of the exhaust moist air. Using real operating data from a major Swedish mill, optimal energy conservation strategies were investigated using different heat pump systems in paper drying. Simulation results are compared for compressor-driven and absorption heat pump systems. An absorption heat transformer was also investigated. A CH3OH-LiBr double-lift cycle would have a low COP value due to the low temperature of the moist air stream and the restricted temperature of the cooling water available. A total of 30 MW thermal equivalent is currently needed in the mill at a temperature of 75 degrees C for mixing-pits, district heating and a log store. Exhaust humid air at a temperature of 54 degrees C from only three of the paper machines was used in this study. SHPUMP simulations revealed that installing a mechanical heat pump unit using HFC 134a would result in a recovery of 22 MW due to the temperature level of this application. On the other hand, 12 MW can be recovered with an absorption heat pump. To optimize the operating conditions, H2O-NaOH was selected as the best of three based on exergy index criteria. Assuming a steam cost of 22 $/MW h and an electricity cost of 32 $/MW h, the pay-off periods would be 3.3 and 2.9 years for compressor-driven and absorption heat pump alternatives, respectively. (C) 1997 by John Wiley & Sons, Ltd.
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3. |
- Ahlström, Johan, 1990, et al.
(författare)
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Bark as feedstock for dual fluidized bed gasifiers. Operability, efficiency, and economics
- 2019
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 43:3, s. 1171-1190
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Tidskriftsartikel (refereegranskat)abstract
- The demand for biofuels and biochemicals is expected to increase in the future, which will in turn increase the demand for biomass feedstock. Large gasification plants fueled with biomass feedstock are likely to be a key enabling technology in a resource-efficient, bio-based economy. Furthermore, the costs for producing biofuels and biochemicals in such plants could potentially be decreased by utilizing inexpensive low-grade residual biomass as feedstock. This study investigates the usage of shredded tree bark as a feedstock for the production of biomethane in the GoBiGas demonstration plant in Gothenburg, Sweden, based on a 32 MWth industrial dual fluidized bed gasification unit. The plant was operated with bark feedstock for 12 000 hours during the period 2014 to 2018. Data from the measurement campaign were processed using a stochastic approach to establish the plant's mass and energy balances, which were then compared with operation of the plant with wood pellets. For this comparison, an extrapolation algorithm was developed to predict plant performance using bark dried to the same moisture content as wood pellets, ie, 8%w.b. Plant operation with bark feedstock was evaluated for operability, efficiency, and feedstock-related cost. The gas quality achieved during the test period was similar to that obtained for operation with wood pellets. Furthermore, no significant ash sintering or agglomeration problems were observed more than 750 hours of operation. The calculated biomass-to-biomethane efficiency is 43% to 47% (lower heating value basis) for operation with wet bark. However, the predicted biomass-to-biomethane efficiency can be increased to 55%–65% for operation with bark feedstock dried to 8% moisture content, with corresponding feedstock costs in the range of 24.2 to 32.7 EUR/MWh; ie, a cost reduction of about 40% compared with wood pellets.
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4. |
- Alamia, Alberto, 1984, et al.
(författare)
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Performance of large-scale biomass gasifiers in a biorefinery, a state-of-the-art reference
- 2017
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 41:14, s. 2001-2019
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Tidskriftsartikel (refereegranskat)abstract
- The Gothenburg Biomass Gasification plant (2015) is currently the largest plant in the world producing biomethane (20 MWbiomethane) from woody biomass. We present the experimental data from the first measurement campaign and evaluate the mass and energy balances of the gasification sections at the plant. Measures improving the efficiency including the use of additives (potassium and sulfur), high-temperature pre-heating of the inlet streams, improved insulation of the reactors, drying of the biomass and introduction of electricity as a heat source (power-to-gas) are investigated with simulations. The cold gas efficiency was calculated in 71.7%LHVdaf using dried biomass (8% moist). The gasifier reaches high fuel conversion, with char gasification of 54%, and the fraction of the volatiles is converted to methane of 34%mass. Because of the design, the heat losses are significant (5.2%LHVdaf), which affect the efficiency. The combination of potential improvements can increase the cold gas efficiency to 83.5%LHVdaf, which is technically feasible in a commercial plant. The experience gained from the Gothenburg Biomass Gasification plant reveals the strong potential biomass gasification at large scale.
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6. |
- Andersson, Viktor, 1983, et al.
(författare)
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Integration of algae-based biofuel production with an oil refinery: Energy and carbon footprint assessment
- 2020
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 44:13, s. 10860-10877
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Tidskriftsartikel (refereegranskat)abstract
- Biofuel production from algae feedstock has become a topic of interest in the recent decades since algae biomass cultivation is feasible in aquaculture and does therefore not compete with use of arable land. In the present work, hydrothermal liquefaction of both microalgae and macroalgae is evaluated for biofuel production and compared with transesterifying lipids extracted from microalgae as a benchmark process. The focus of the evaluation is on both the energy and carbon footprint performance of the processes. In addition, integration of the processes with an oil refinery has been assessed with regard to heat and material integration. It is shown that there are several potential benefits of co-locating an algae-based biorefinery at an oil refinery site and that the use of macroalgae as feedstock is more beneficial than the use of microalgae from a system energy performance perspective. Macroalgae-based hydrothermal liquefaction achieves the highest system energy efficiency of 38.6%, but has the lowest yield of liquid fuel (22.5 MJ per 100 MJalgae) with a substantial amount of solid biochar produced (28.0 MJ per 100 MJalgae). Microalgae-based hydrothermal liquefaction achieves the highest liquid biofuel yield (54.1 MJ per 100 MJalgae), achieving a system efficiency of 30.6%. Macro-algae-based hydrothermal liquefaction achieves the highest CO2 reduction potential, leading to savings of 24.5 resp 92 kt CO2eq/year for the two future energy market scenarios considered, assuming a constant feedstock supply rate of 100 MW algae, generating 184.5, 177.1 and 229.6 GWhbiochar/year, respectively. Heat integration with the oil refinery is only possible to a limited extent for the hydrothermal liquefaction process routes, whereas the lipid extraction process can benefit to a larger extent from heat integration due to the lower temperature level of the process heat demand.
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7. |
- Arjmand, Mehdi, et al.
(författare)
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Exergetic efficiency of high-temperature-lift chemical heat pump (CHP) based on CaO/CO2 and CaO/H2O working pairs
- 2013
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Ingår i: International Journal of Energy Research. - : Wiley-Blackwell. - 0363-907X .- 1099-114X. ; 37:9, s. 1122-1131
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Tidskriftsartikel (refereegranskat)abstract
- The use of reversible chemical reactions in recuperation of heat has gained significant interest due to higher magnitude of reaction heat compared to that of the latent or sensible heat. To implement chemical reactions for upgrading heat, a chemical heat pump (CHP) may be used. A CHP uses a reversible chemical reaction where the forward and the reverse reactions take place at two different temperatures, thus allowing heat to be upgraded or degraded depending on the mode of operation. In this work, an exergetic efficiency model for a CHP operating in the temperature-level amplification mode has been developed. The first law and the exergetic efficiencies are compared for two working pairs, namely, CaO/CO2 and CaO/H2O for high-temperature high-lift CHPs. The exergetic efficiency increases for both working pairs with increase in task, TH, decrease in heat source, TM, and increase in condenser, TL, temperatures. It is also observed that the difference in reaction enthalpies and specific heats of the involving reactants affects the extent of increase or decrease in the exergetic efficiency of the CHP operating for temperature-level amplification.
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8. |
- Axelsson, Erik Marcus Kristian, 1974, et al.
(författare)
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Profitability and off-site CO2-emission reduction from energy savings in the pulp and paper industry in different future energy markets
- 2012
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 36:9, s. 975-986
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Tidskriftsartikel (refereegranskat)abstract
- Previous studies by the authors have shown that energy savings in pulp and paper mills offer opportunities forincreased electricity production on-site or wood fuel export. The energy export implies reductions in CO2 emissions off-site, where fossil fuel or fossil-fuel-based electricity is replaced. To assess this potential and the related profitability for a future situation, four energy market scenarios were used. For a typical Scandinavian mill, the potential for CO2-emission reductions was 15–140 kton year-1 depending on the scenario and the form of energy export. Extrapolated to all relevant mills in Sweden, the potential was 0.4–3.1 Mton year-1, which is in the order of percent of the Swedish CO2 emissions. Wood fuel export implies larger reduction in CO2 emissions in most scenarios. In contrast, electricity export showed better economy in most of the cases studied; with annual earnings of 5–6Mh, this is an economically robust option. In the market pulp mill investigated, the wood fuel export was in the form of lignin. Lignin could possibly be valued as oil, regarding both price and potential for CO2-emissionreduction, making lignin separation an option with good profitability and large reductions of CO2 emissions.
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9. |
- Börjesson, Martin, 1980, et al.
(författare)
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Assessment of transport fuel taxation strategies through integration of road transport in an energy system model — the case of Sweden
- 2012
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 1099-114X .- 0363-907X. ; 36:5, s. 648-669
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Tidskriftsartikel (refereegranskat)abstract
- Road transport is responsible for a large and growing share of CO2 emissions in most countries. A number of new fuel-efficient vehicle technologies and renewable transport fuels are possible alternatives to conventional options but their deployment relies strongly on different policy measures. Even though a future higher use of transport biofuels and electric vehicles is likely to increase the interaction between the transportation sector and the stationary energy system (heat, power, etc.), these systems are often analysed separately. In this study, a transport module is developed and integrated into the MARKAL_Nordic energy system model. The transport module describes a range of vehicle technologies and fuel options as well as different paths for conversion of primary energy resources into transport fuels. The integrated model is utilized to analyse the impact of transport fuel tax designs on future cost-effective fuel and technology choices in the Swedish transportation sector, as well as the consequences of these choices on system costs and CO2 emissions. The model, which is driven by cost-minimization, is run to 2050 with various assumptions regarding transport fuel tax levels and tax schemes. The results stress the importance of fuel taxes to accelerate the introduction of fuel-efficient vehicle technologies such as hybrids and plug-in hybrids. Tax exemptions can make biofuels an economically favourable choice for vehicle users. However, due to limitations in biomass supply, a too strong policy-focus on transport biofuels can lead to high system costs in relation to the CO2 abatement achieved. The modelling performed indicates that the effects caused by linkages between the transportation sector and the stationary energy system can be significant and integrated approaches are thus highly relevant.
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10. |
- Carlson, Annelie
(författare)
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On cost-effective technical measures to avoid environmental damage of regional energy systems
- 2002
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 0363-907X .- 1099-114X. ; 26:12, s. 1103-1115
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Tidskriftsartikel (refereegranskat)abstract
- The production of heat and electricity can cause large environmental impacts and, hence, large costs for society. Those are costs that are seldom taken into consideration. An important question is how the future technical energy systems should be formed if environmental costs were considered as any other good or service, such as raw material, capital and labour. This study comprises cost-effective technical measures when monetary values of external effects are included in an energy system analysis. It is an analysis of how the present energy system can for society be cost-effectively reconstructed to be more sustainable. A regional energy system model has been developed to perform the study and it concentrates upon production of heat in single-family houses, multi-dwelling buildings, non-residential promises and district heating systems. The analysis adopts a business economic perspective, using present prices of energy carriers, and a more socio-economic perspective, in which external costs are included. The result of the analysis is the optimal mix of energy carriers as well as new and existing heating plants that minimizes the costs of satisfying a demand for heat. The results show that it is profitable to invest in new heating plants fuelled with woody biomass. Furthermore, the external costs arising with satisfying the demand for heat can decrease substantially, 60%, by carrying through with the investments that are cost-effective according to the institutional rules valid today. When monetary values of external costs are taken into consideration, this number is additional 5-percentage points lower. It is shown that if environmental costs are included it is more expensive to continue with business as usual than it is to reconstruct and run a more sustainable energy system.
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