| 1. |
- Olsson, Henrik, et al.
(författare)
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Self-discharge Reactions in Energy Storage Devices Based on Polypyrrole-cellulose Composite Electrodes
- 2014
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Ingår i: Green. - : Walter de Gruyter GmbH. - 1869-8778 .- 1869-876X. ; 4:1-6, s. 27-39
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Tidskriftsartikel (refereegranskat)abstract
- The self-discharge behavior of organic electrodes and symmetric devices for sustainable energy storage, composed of electrodes containing a thin layer of polypyrrole coated onto a high surface area cellulose matrix, has been studied for the first time using different electrode sizes and electrolytes. Experimental data from open circuit measurements of the individual electrode potentials of charged symmetrical two-electrode energy storage devices as a function of time were evaluated based on three different self-discharge models. This evaluation clearly showed that the self-discharge process of the positive electrode is governed by a previously undetected activation-controlled faradaic reaction while the self-discharge of the negative electrode is due to diffusion controlled oxidation involving oxygen dissolved in the electrolyte. Potentiostatic three-electrode measurements and spectroelectrochemical experiments also showed that protons as well as maleimide were released from positively polarized polypyrrole electrodes. These new findings clearly show that the self-discharge of the cells originate from two different types of reactions on the positive and negative electrodes and that the main contribution to the self-discharge of the cells comes from an activation controlled reaction involving the positive electrode. These results provide an improved understanding of polypyrrole based devices and also yield new possibilities for the development of stable conducting polymer system for energy storage applications.
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| 2. |
- Thapper, Anders, et al.
(författare)
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Artificial Photosynthesis for Solar Fuels – an Evolving Research Field within AMPEA, a Joint Programme of the European Energy Research Alliance
- 2013
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Ingår i: Green. - : Walter de Gruyter GmbH. - 1869-8778 .- 1869-876X. ; 3:1, s. 43-57
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Tidskriftsartikel (refereegranskat)abstract
- On the path to an energy transition away from fossil fuels to sustainable sources, the European Union is for the moment keeping pace with the objectives of the Strategic Energy Technology-Plan. For this trend to continue after 2020, scientific breakthroughs must be achieved. One main objective is to produce solar fuels from solar energy and water in direct processes to accomplish the efficient storage of solar energy in a chemical form. This is a grand scientific challenge. One important approach to achieve this goal is Artificial Photosynthesis. The European Energy Research Alliance has launched the Joint Programme “Advanced Materials & Processes for Energy Applications” (AMPEA) to foster the role of basic science in Future Emerging Technologies. European researchers in artificial photosynthesis recently met at an AMPEA organized workshop to define common research strategies and milestones for the future. Through this work artificial photosynthesis became the first energy research sub-field to be organised into what is designated “an Application” within AMPEA. The ambition is to drive and accelerate solar fuels research into a powerful European field – in a shorter time and with a broader scope than possible for individual or national initiatives. Within AMPEA the Application Artificial Photosynthesis is inclusive and intended to bring together all European scientists in relevant fields. The goal is to set up a thorough and systematic programme of directed research, which by 2020 will have advanced to a point where commercially viable artificial photosynthetic devices will be under development in partnership with industry.
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| 3. |
- Romanelli, F., et al.
(författare)
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Fusion energy research for ITER and beyond
- 2011
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Ingår i: Green. - 1869-876X. ; 1:3-4, s. 249-261
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Forskningsöversikt (refereegranskat)abstract
- The achievement in the last two decades of controlled fusion in the laboratory environment is opening the way to the realization of fusion as a source of sustainable, safe and environmentally responsible energy. The next step towards this goal is the construction of the International Thermonuclear Experimental Reactor (ITER), which aims to demonstrate net fusion energy production on the reactor scale. This paper reviews the current status of magnetic confinement fusion research in view of the ITER project and provides an overview of the main remaining challenges on the way towards the realization of commercial fusion energy production in the second half of this century.
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