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- Chateau, Denis, et al.
(författare)
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Silica hybrid sol-gel materials with unusually high concentration of Pt-organic molecular guests : Studies of luminescence and nonlinear absorption of light
- 2012
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Ingår i: ACS Applied Materials and Interfaces. - Washington : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 4:5, s. 2369-2377
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Tidskriftsartikel (refereegranskat)abstract
- The development of new photonic materials is a key step towards improvement of existing optical devices and for the preparation of a new generation of systems. Therefore synthesis of photonic hybrid materials with a thorough understanding and control of the microstructure-to-properties relationships is crucial. In this perspective, a new preparation method based on fast gelation reactions using simple dispersion of dyes without strong covalent bonding between dye and matrix has been developed. This new sol-gel method is demonstrated through synthesis of monolithic siloxane-based hybrid materials highly doped by various platinum(II) acetylide derivatives. Concentrations of the chromophores as high as 400 mM were obtained and resulted in unprecedented optical power limiting (OPL) performance at 532 nm of the surface-polished solids. Static and time-resolved photoluminescence of the prepared hybrid materials were consistent with both OPL data and previous studies of similar Pt(II) compounds in solution. The impacts of the microstructure and the chemical composition of the matrix on the spectroscopic properties, are discussed.
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- Hällstig, Emil, et al.
(författare)
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Retrocommunication utilizing electroabsorption modulators and non-mechanical beam steering
- 2005
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Ingår i: Optical Engineering. - : SPIE-Intl Soc Optical Eng. - 0091-3286 .- 1560-2303. ; 44:4, s. 045001-
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Tidskriftsartikel (refereegranskat)abstract
- A novel retrocommunication link utilizing reflective multiplequantum well (MQW) optical modulators and nonmechanical beamsteering and tracking is demonstrated. Large aperture reflective MQWmodulators using AlGaAs/GaAs are optimized and manufactured. Themodulators exhibit a contrast ratio larger than 4:1 and a modulationbandwidth of 10 MHz. Nonmechanical beam steering and tracking arestudied using nematic liquid crystal (NLC) spatial light modulators(SLMs). The communication link is comprised of a retromodulating arraywith four MQW modulators and a transceiver using a NLC SLM for beamsteering and tracking. Transfer of audio, real-time image data and pseudorandombit sequences over 100-m range while tracking the movingretromodulator is shown. The link is capable of transferring data at approximately8 Mbps.
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4. |
- Sjöqvist, Lars, et al.
(författare)
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A novel free-space retro-communication link
- 2004
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Ingår i: Proceedings of SPIE - The International Society for Optical Engineering. - : SPIE. - 0277-786X .- 1996-756X. ; 5614, s. 10-23
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Retrocommunication is a new technique for asymmetric free-space optical communication that has attracted interest during recent years. Novel technologies such as multiple quantum well (MQW) optical modulators and non-mechanical laser beam steering and tracking have been studied for implementation in a retrocommunication link. Large and small aperture reflective AlGaAs/GaAs MQW modulators were optimised and fabricated. The modulators exhibit high contrast ratios (from 5 to 100) and high modulation rates (up to 16 Mbit/s). A retroreceiver consisting of four large aperture MQW modulators, associated optics and drive electronics was fabricated. Nematic liquid crystal spatial light modulators have been evaluated, characterised for beam steering and tracking and implemented in a transceiver. Small area MQW modulators, used in focal plane configurations, were studied for static communication links. Results from a novel retrocommunication link utilising a retroreceiver and non-mechanical laser beam steering and tracking will be presented. Bit rates of 8 Mbit/s were observed during non-mechanical tracking of a moving retroreceiver over 100 m range. The demonstrator system was capable of transferring audio-, real-time images or bit streams. The demonstrated principles show promising features for future low weight free-space communication links. Performance calculations including requirements for a retrocommunication link using MQW modulators and non-mechanical beam steering are discussed.
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5. |
- Steinvall, Ove, et al.
(författare)
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Laser dazzling impacts on car driver performance
- 2013
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Konferensbidrag (refereegranskat)abstract
- A growing problem for the Police and Security Forces has been to prevent potentially hostile individuals to pass a checkpoint, without using lethatl violence. Therefore the question has been if there is a laser or any other strong light source that could be used as a warning and dazzling device, without lethal or long term effects. To investigate the possibilities a field trial has been performed at a motor-racing track. A green CW laser with an irradiance on the eye of maximum 0.5 MPE, as defined by ICNIRP [1] and the ANZI standard [2], was used as a dazzle source. Ten drivers have been driving with dipped headlights through a course of three lines with orange cones. In every line there has been only one gate wide enough to pass without hitting the cones. The time through the course, the choice of gates and the number of cones hit have been measured. For every second trial drive through the track, the driver was exposed to the laser dazzler. The background illuminances ranged from a thousand lux in daylight to about ten millilux in darkness. The protective effect of the sun-visor of the car was investigated. The drives visual system was carefully examined before and after experimental driving and a few weeks after the experimental driving to verify that no pathological effects, that could potentially be induced by the laser exposure, pre-existed or occurred after the laser exposure. An analysis of variance for a within subjects design has been used for evaluation. It was found that green laser light can have an obvious warning effect in daylight. Dazzling does reduce the drivers ability to make judgments and manouver the car in twilight and darkness. A sun-visor can reduce the glare and give the driver an improved control, but that perception can be unjustified. No damage to the visual system was observed.
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7. |
- Westlund, Robert, 1979-, et al.
(författare)
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Efficient Nonlinear Absorbing Platinum(II) Acetylide Chromophores in Solid PMMA Matrices
- 2008
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Ingår i: Advanced Functional Materials. - : Wiley. - 1616-301X .- 1616-3028. ; 18:13, s. 1939-1948
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Tidskriftsartikel (refereegranskat)abstract
- Platinum(II) acetylides were incorporated into poly(methyl methacrylate) (PMMA) glasses to obtain solid-state nonlinear optical devices. We report on device fabrication, structural, chemical, and mechanical properties, as well as the optical limiting capabilities of the final solids. Two different guest-host systems are presented: 1) Dye molecules functionalized to be readily dispersed in methyl methacrylate (MMA) and subsequent in situ polymerization of the MMA yielding solid PMMA host matrices. 2) Dye molecules functionalized to copolymerize with MMA forming covalent bonds between the guest and the PMMA host matrix. A range of doped organic solids were prepared, reaching concentrations up to 13 wt% of the guest molecule. Raman spectra of the doped solid devices indicate that the chemical structure of the nonlinear dyes remains intact upon the polymerization of the solid matrix. Luminescence spectra confirm that the basic photophysical properties observed for the same solute molecules in THF are maintained also in the solid state. Optical power limiting (OPL) characterization reveal clamping levels for the dyes nonbonded to the solid host being less than 4 μJ at pulse energies up to 110 μJ at 532 nm (f/5 arrangement and 5 ns pulses), which is comparable to the performance of similar dyes in THF solutions. In contrast, the highly crosslinked solid possesses a higher clamping level (8 μj) at the same nominal concentration.
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8. |
- Yu, Zhaohua, 1983-, et al.
(författare)
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Green light laser exposure at 532nm near the exposure limit during a human volunteer vehicle driving task does not alter structure or function in the visual system
- 2014
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Ingår i: Journal of laser applications. - Melville : Laser Institute of America. - 1042-346X .- 1938-1387. ; 26:2, s. 022009-1-022009-7
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Tidskriftsartikel (refereegranskat)abstract
- This study aimed to verify nonexistence of clinically important pathological effects to the visual system after exposure to 532 nm green laser light close to the exposure limit. The present medical surveillance of vision and visual health reported in this paper is the conjunction with a study of driver performance in the presence of 532 nm laser induced glare. The driving time varied between 25 and 55 s, depending on background luminance. The laser was on during the complete test drive. The peak corneal irradiance typically was 3.5Wm2 in one test drive. Considering a typical test drive, the typical time integrated corneal radiant exposure for one test drive was estimated to be 53 J/m2. The number of test drives varied among drivers but was typically 50, thus resulting in a cumulative corneal exposure dose of approximately 2.7 kJ/m2. Altogether, ten subjects were recruited according to inclusion and exclusion criteria. All ten subjects were examined for visual acuity, intraocular pressure, contrast sensitivity, color vision, monocular reading speed, and eye structure with clinical slit-lamp microscopy examination and indirect retinoscopy. All subjects were examined before exposure, immediately after exposure, and finally within an interval between 1 week and 4 weeks after exposure. There was no significant change of visual acuity, intraocular pressure, contrast sensitivity, color vision, or monocular reading speed between before and after exposure. No abnormal ocular structure was detected after exposure. This study demonstrates that close to exposure limit, exposure to 532 nm green laser light during a vehicle driving task does not induce structural or functional damage to the human visual system as observed in the interval minutes to weeks after exposure.
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