| 1. |
- Abbondanza, Giuseppe, 1991, et al.
(författare)
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Au-Pd Barcode Nanowires with Tailored Lattice Parameters and Segment Lengths for Catalytic Applications
- 2024
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Ingår i: ACS Applied Nano Materials. - 2574-0970. ; 7:4, s. 3861-3874
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Tidskriftsartikel (refereegranskat)abstract
- In this study, we present a systematic investigation of the controlled fabrication of Au-Pd barcode nanowires within nanoporous anodic aluminum oxide (NP-AAO) templates. By using a combination of in situ X-ray diffraction (XRD), focused ion beam scanning electron microscopy (FIB-SEM), and transmission electron microscopy (TEM), we elucidate the influence of template preparation methods on the resulting nanowire properties. The template treatment, involving either pore widening or barrier layer thinning, significantly impacts nanowire growth. Through the analysis of the XRD data, we observe sequential deposition of Au and Pd segments with lattice parameter variations and strain effects. Particularly, the lattice parameters of Au and Pd segments display intricate temporal dependencies, influenced by interfacial effects and strain caused by growth under confinement. FIB-SEM imaging reveals uniform and reproducible nanowire lengths in the template treated with pore widening. Furthermore, TEM analysis confirms the presence of distinct Au and Pd segments, while scanning TEM-energy-dispersive X-ray spectroscopy revealed minor evidence of interdiffusion between the first and the second electrodeposited segments. Our findings emphasize the potential of the electrodeposition process within nanoporous templates for producing barcode nanowires with precise segmental properties. The combination of in situ XRD and electron microscopy offers valuable insights into the growth dynamics and structural characteristics of the fabricated Au-Pd barcode nanowires. This controlled fabrication strategy opens doors to tailoring nanowire properties for diverse applications, particularly in catalysis.
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| 2. |
- Abbondanza, Giuseppe, 1991, et al.
(författare)
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Hydride formation and dynamic phase changes during template-assisted Pd electrodeposition
- 2023
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Ingår i: Nanotechnology. - 1361-6528 .- 0957-4484. ; 34:50
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Tidskriftsartikel (refereegranskat)abstract
- We investigated the structural evolution of electrochemically fabricated Pd nanowires in situ by means of grazing-incidence transmission small- and wide-angle x-ray scattering (GTSAXS and GTWAXS), x-ray fluorescence (XRF) and two-dimensional surface optical reflectance (2D-SOR). This shows how electrodeposition and the hydrogen evolution reaction (HER) compete and interact during Pd electrodepositon. During the bottom-up growth of the nanowires, we show that beta-phase Pd hydride is formed. Suspending the electrodeposition then leads to a phase transition from beta-phase Pd hydride to alpha-phase Pd. Additionally, we find that grain coalescence later hinders the incorporation of hydrogen in the Pd unit cell. GTSAXS and 2D-SOR provide complementary information on the volume fraction of the pores occupied by Pd, while XRF was used to monitor the amount of Pd electrodeposited.
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