| 1. |
- Abbas, Ghazanfar, et al.
(author)
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Electrochemical investigation of mixed metal oxide nanocomposite electrode for low temperature solid oxide fuel cell
- 2017
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In: International Journal of Modern Physics B. - : WORLD SCIENTIFIC PUBL CO PTE LTD. - 0217-9792. ; 31:27
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Journal article (peer-reviewed)abstract
- Zinc-based nanostructured nickel (Ni) free metal oxide electrode material Zn-0.60/CU0.20Mn0.20 oxide (CMZO) was synthesized by solid state reaction and investigated for low temperature solid oxide fuel cell (LTSOFC) applications. The crystal structure and surface morphology of the synthesized electrode material were examined by XRD and SEM techniques respectively. The particle size of ZnO phase estimated by Scherer's equation was 31.50 nm. The maximum electrical conductivity was found to be 12.567 S/cm and 5.846 S/cm in hydrogen and air atmosphere, respectively at 600 degrees C. The activation energy of the CMZO material was also calculated from the DC conductivity data using Arrhenius plots and it was found to be 0.060 and 0.075 eV in hydrogen and air atmosphere, respectively. The CMZO electrode-based fuel cell was tested using carbonated samarium doped ceria composite (NSDC) electrolyte. The three layers 13 mm in diameter and 1 mm thickness of the symmetric fuel cell were fabricated by dry pressing. The maximum power density of 728.86 mW/cm(2) was measured at 550 degrees C.
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| 2. |
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| 3. |
- Sarfraz, Amina, et al.
(author)
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Catalytic Effect of Silicon Carbide on the Composite Anode of Fuel Cells
- 2021
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In: ACS Applied Energy Materials. - : AMER CHEMICAL SOC. - 2574-0962. ; 4:7, s. 6436-6444
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Journal article (peer-reviewed)abstract
- High efficiency, fuel flexibility, and sustainable energy conversion make fuel cells attractive compared to conventional energy systems. The direct ethanol fuel cells have attracted much attention because of the direct utilization of ethanol fuel. Anode materials are required to enhance the catalytic activity of the liquid fuel, which oxidize the fuel at lower operating temperature. Therefore, the catalytic effect using silicon carbide has been investigated in the LiNiO2-delta anode. The material has been characterized, and it is found that SiC shows a cubic structure and LiNiO2-delta exhibits a hexagonal structure, while the LiNiO2-delta-SiC composite exhibits a mixed cubic and hexagonal phase. Scanning electron microscopy depicts that the material is porous. The Fourier transform infrared spectroscopy analysis shows the presence of Si-O-Si, Si-C, C=O, and Si-OH bonding. The LiNiO2-delta-SiC composite (1:0.3) exhibited a maximum electrical conductivity of 1.34 S cm(-1) at 650 degrees C with an electrical band gap of 0.84 eV. The fabricated cell with the LiNiO2-delta-SiC anode exhibits a power density of 0.20 W cm(-2) at 650 degrees C with liquid ethanol fuel. The results show that there is a promising catalytic activity of SiC in the fuel cell anode.
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| 4. |
- Abbas, Ghazanfar, et al.
(author)
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Electrochemical study of nanostructured electrode for low-temperature solid oxide fuel cell (LTSOFC)
- 2014
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In: International Journal of Energy Research. - : Hindawi Limited. - 0363-907X .- 1099-114X. ; 38:4, s. 518-523
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Journal article (peer-reviewed)abstract
- Zn-based nanostructured Ba0.05Cu0.25Fe0.10Zn0.60O (BCFZ) oxide electrode material was synthesized by solid-state reaction for low-temperature solid oxide fuel cell. The cell was fabricated by sandwiching NK-CDC electrolyte between BCFZ electrodes by dry press technique, and its performance was assessed. The maximum power density of 741.87 mW-cm(-2) was achieved at 550 degrees C. The crystal structure and morphology were characterized by X-ray diffractometer (XRD) and SEM. The particle size was calculated to be 25 nm applying Scherer's formula from XRD data. Electronic conductivities were measured with the four-probe DC method under hydrogen and air atmosphere. AC Electrochemical Impedance Spectroscopy of the BCFZ oxide electrode was also measured in hydrogen atmosphere at 450 degrees C.
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| 5. |
- Afroz, Laila, et al.
(author)
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Nanocomposite Catalyst (1 – x)NiO-xCuO/yGDC for Biogas Fueled Solid Oxide Fuel Cells
- 2023
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In: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 6:21, s. 10918-10928
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Journal article (peer-reviewed)abstract
- The composites of Ni–Cu oxides with gadolinium doped ceria (GDC) are emerging as highly proficient anode catalysts, owing to their remarkable performance for solid oxide fuel cells operated with biogas. In this context, the nanocomposite catalysts (1 – x)NiO-xCuO/yGDC (x = 0.2–0.8; y = 1,1.3) are synthesized using a solid-state reaction route. The cubic and monoclinic structures are observed for NiO and CuO phases, respectively, while CeO2 showed cubic fluorite structure. The scanning electron microscopic images revealed a rise in the particle size with an increase in the copper and GDC concentration. The optical band gap values are calculated in the range 2.82–2.33 eV from UV–visible analysis. The Raman spectra confirmed the presence of vibration modes of CeO2 and NiO. The electrical conductivity of the nanocomposite anodes is increased as the concentration of copper and GDC increased and reached at 9.48 S cm–1 for 0.2NiO-0.8CuO/1.3GDC composition at 650 °C. The electrochemical performance of (1 – x)NiO-xCuO/yGDC (x = 0.2–0.8; y = 1,1.3)-based fuel cells is investigated with biogas fuel at 650 °C. Among all of the as-synthesized anodes, the fuel cell with composition 0.2NiO-0.8CuO/1.3GDC showed the best performance, such as an open circuit voltage of 0.84 V and peak power density of 72 mW cm–2. However, from these findings, it can be inferred that among all other compositions, the 0.2NiO-0.8CuO/1.3GDC anode is a superior combination for the high electrochemical performance of solid oxide fuel cells fueled with biogas.
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| 6. |
- Ahmad, Ashfaq, et al.
(author)
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Design, Fabrication, and Measurements of Extended L-Shaped Multiband Antenna for Wireless Applications
- 2018
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In: Applied Computational Electromagnetics Society Journal. - : Applied Computational Electromagnetics Society (ACES). - 1054-4887. ; 33:4, s. 388-393
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Journal article (peer-reviewed)abstract
- This article expounds a multi-band compact shaped antenna, which is based on CPW ground plane. FR-4 with a thickness of 1.6 mm is used as a substrate for the proposed antenna. The proposed antenna is capable of operating at 1.56 GHz for (Global Positioning System), 2.45 GHz (Wireless Local Area Network) and 4.49 GHz (Aeronautical Mobile Telemetry (AMT) fixed services). The efficiency at 1.56, 2.45, and 4.49 GHz is 79.7, 76.9 and 76.7%, respectively. The VSWR of the presented antenna is less than 1.5 at all the desired resonance modes, which confirms its good impedance matching. The performance of the proposed antenna is evaluated in terms of VSWR, return loss, radiation pattern and efficiency. CST (R) MWS (R) software is used for simulations. In order to validate the simulation results, a prototype of the designed antenna is fabricated and a good agreement is found between the simulated and measured results.
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| 7. |
- Ahmad, Ashfaq, et al.
(author)
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Flexible and Compact Spiral-Shaped Frequency Reconfigurable Antenna for Wireless Applications
- 2020
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In: IETE Journal of Research. - : TAYLOR & FRANCIS LTD. - 0377-2063 .- 0974-780X. ; 66:1, s. 22-29
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Journal article (peer-reviewed)abstract
- A flexible, spiral-shaped frequency reconfigurable antenna with a compact size (20 x 24 mm(2)) is presented. The proposed antenna has a low-profile planar structure and is able to operate at five different frequency bands, i.e., 4.19-4.48, 5.98-6.4, 3.42-4.0, 5.4-5.68, and 6.8-7.0 GHz. The multiband operation enables the antenna to cover aeronautical radio navigation, fixed satellite communication, WLAN, and WiMAX standards. A radiating element is backed by Rogers (R) 5880 substrate with a thickness of 0.508 mm and dielectric constant of 2.2. The spiral shape is achieved by introducing different strips. Frequency reconfiguration is achieved by the incorporation of a lumped element in a strip, so that the antenna can switch between different resonances. To validate the performance of the antenna, the prototype of the design was fabricated and tested. Good acquiescent is seen between simulated and measured results. The proposed antenna operates efficiently with appreciable return loss, directivity, bandwidth, and peak gain.
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| 8. |
- Ahmad, Muhammad Ashfaq, et al.
(author)
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Structural and electrical characterisation of nanostructure electrodes for SOFCs
- 2014
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In: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 39:30, s. 17487-17491
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Journal article (peer-reviewed)abstract
- This paper reports the effects of sintering temperature on structure, particle size and conductivity of electrodes (Sn0.2Zn0.8Fe0.2O & Sn0.8Zn0.2Fe0.2O). The electrode material was prepared by the chemical method combining a solid state reaction. Structural analyses were performed using X-ray diffraction and scanning electron microscopy. The particle size of the material obtained using Scherrer's formula was 50-60 nm and the nanostructure's surface was studied using electrochemical characterisations tools. Electrical conductivity was determined using the 4-probe DC method, which was compared with the 4-probe AC method. These results suggest a promising substitute for the conventional electrodes of solid oxide fuel cells (SOFCs). It is known that a sintering temperature above 1000 degrees C causes an increase in density and a reduction of porosity. Therefore, we optimised the sintering temperature at 1000 degrees C and obtained electrical conductivity of about 5 S Thus, this electrode could play a vital role in the development of high performance SOFCs at intermediate temperatures.
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| 9. |
- Ahmad, Shafqat, et al.
(author)
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Gene × physical activity interactions in obesity: combined analysis of 111,421 individuals of European ancestry. : combined analysis of 111,421 individuals of European ancestry
- 2013
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In: PLoS Genetics. - : Public Library of Science (PLoS). - 1553-7404. ; 9:7, s. 1003607-1003607
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Journal article (peer-reviewed)abstract
- Numerous obesity loci have been identified using genome-wide association studies. A UK study indicated that physical activity may attenuate the cumulative effect of 12 of these loci, but replication studies are lacking. Therefore, we tested whether the aggregate effect of these loci is diminished in adults of European ancestry reporting high levels of physical activity. Twelve obesity-susceptibility loci were genotyped or imputed in 111,421 participants. A genetic risk score (GRS) was calculated by summing the BMI-associated alleles of each genetic variant. Physical activity was assessed using self-administered questionnaires. Multiplicative interactions between the GRS and physical activity on BMI were tested in linear and logistic regression models in each cohort, with adjustment for age, age(2), sex, study center (for multicenter studies), and the marginal terms for physical activity and the GRS. These results were combined using meta-analysis weighted by cohort sample size. The meta-analysis yielded a statistically significant GRS × physical activity interaction effect estimate (Pinteraction = 0.015). However, a statistically significant interaction effect was only apparent in North American cohorts (n = 39,810, Pinteraction = 0.014 vs. n = 71,611, Pinteraction = 0.275 for Europeans). In secondary analyses, both the FTO rs1121980 (Pinteraction = 0.003) and the SEC16B rs10913469 (Pinteraction = 0.025) variants showed evidence of SNP × physical activity interactions. This meta-analysis of 111,421 individuals provides further support for an interaction between physical activity and a GRS in obesity disposition, although these findings hinge on the inclusion of cohorts from North America, indicating that these results are either population-specific or non-causal.
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| 10. |
- Ahmad, Shafqat, et al.
(author)
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Gene x physical activity interactions in obesity : combined analysis of 111,421 individuals of European ancestry
- 2013
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In: PLOS Genetics. - : Public Library of Science. - 1553-7390 .- 1553-7404. ; 9:7, s. e1003607-
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Journal article (peer-reviewed)abstract
- Numerous obesity loci have been identified using genome-wide association studies. A UK study indicated that physical activity may attenuate the cumulative effect of 12 of these loci, but replication studies are lacking. Therefore, we tested whether the aggregate effect of these loci is diminished in adults of European ancestry reporting high levels of physical activity. Twelve obesity-susceptibility loci were genotyped or imputed in 111,421 participants. A genetic risk score (GRS) was calculated by summing the BMI-associated alleles of each genetic variant. Physical activity was assessed using self-administered questionnaires. Multiplicative interactions between the GRS and physical activity on BMI were tested in linear and logistic regression models in each cohort, with adjustment for age, age(2), sex, study center (for multicenter studies), and the marginal terms for physical activity and the GRS. These results were combined using meta-analysis weighted by cohort sample size. The meta-analysis yielded a statistically significant GRS x physical activity interaction effect estimate (P-interaction = 0.015). However, a statistically significant interaction effect was only apparent in North American cohorts (n = 39,810, P-interaction = 0.014 vs. n = 71,611, P-interaction = 0.275 for Europeans). In secondary analyses, both the FTO rs1121980 (P-interaction = 0.003) and the SEC16B rs10913469 (P-interaction = 0.025) variants showed evidence of SNP x physical activity interactions. This meta-analysis of 111,421 individuals provides further support for an interaction between physical activity and a GRS in obesity disposition, although these findings hinge on the inclusion of cohorts from North America, indicating that these results are either population-specific or non-causal.
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